huot_1991#
J. Huot and T. K. Bose, “Experimental determination of the dielectric virial coefficients of atomic gases as a function of temperature”, J. Chem. Phys. 95, 2683 (1991)
Source record · Catalogue · Review register
DOI: 10.1063/1.461801
Source kind: measurement
Recorded technique: Capacitance (dielectric) measurements on He, Ne, Ar, Kr and Xe at 77.4, 242.95, 303.15, 323.15 and 407.6 K up to about 400 bar, by the expansion method: the second and third dielectric virial coefficients B_eps and C_eps from the slope and curvature of the combined expansion curves (Eq. 12).
Materials in structured entries: Ar, He, Kr, Ne, Xe
Dataset quantities: refractivity_virial_coefficient
Contents: 28 datasets; 0 formulas.
Curation notes#
Identity VALIDATED_WITH_WARNINGS by the library. Printed pp. 2683-2687; Table I is on pdf p. 5.
TABLE I (image checked against the cells, 2026-10-01): B_eps (cm^6/mol^2) and C_eps (cm^9/mol^3), static, per gas and temperature; cells printed ‘...’ are absent. Extracted, one dataset per coefficient and temperature, as refractivity_virial_coefficient of order 2 and 3 at the static limit. No confidence level is stated for the ‘+-’ values (level: not stated). The text gives A_eps of neon, 0.9969(3) cm^3/mol at 323.15 K, not extracted.
These are dielectric (static) coefficients: for the atoms the optical B_R differs from B_eps by the dispersion of the pair term, a few per cent (OEP 4, section 4.1).
Recorded bibliographic identity status: VALIDATED_WITH_WARNINGS. This concerns identification of the source; it does not establish the scientific correctness of its contents.
Datasets#
huot_1991/B_eps_77.4_He#
{
"id": "B_eps_77.4_He",
"material": "He",
"file": "He/huot_1991__B_eps_77.4_He.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 77.4
}
}
B_eps of Table I at 77.4 K, static (dielectric).
huot_1991/C_eps_77.4_He#
{
"id": "C_eps_77.4_He",
"material": "He",
"file": "He/huot_1991__C_eps_77.4_He.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 77.4
}
}
C_eps of Table I at 77.4 K, static (dielectric).
huot_1991/B_eps_242.95_He#
{
"id": "B_eps_242.95_He",
"material": "He",
"file": "He/huot_1991__B_eps_242.95_He.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 242.95
}
}
B_eps of Table I at 242.95 K, static (dielectric).
huot_1991/C_eps_242.95_He#
{
"id": "C_eps_242.95_He",
"material": "He",
"file": "He/huot_1991__C_eps_242.95_He.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 242.95
}
}
C_eps of Table I at 242.95 K, static (dielectric).
huot_1991/B_eps_323.15_He#
{
"id": "B_eps_323.15_He",
"material": "He",
"file": "He/huot_1991__B_eps_323.15_He.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 323.15
}
}
B_eps of Table I at 323.15 K, static (dielectric).
huot_1991/C_eps_323.15_He#
{
"id": "C_eps_323.15_He",
"material": "He",
"file": "He/huot_1991__C_eps_323.15_He.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 323.15
}
}
C_eps of Table I at 323.15 K, static (dielectric).
huot_1991/B_eps_77.4_Ne#
{
"id": "B_eps_77.4_Ne",
"material": "Ne",
"file": "Ne/huot_1991__B_eps_77.4_Ne.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 77.4
}
}
B_eps of Table I at 77.4 K, static (dielectric).
huot_1991/C_eps_77.4_Ne#
{
"id": "C_eps_77.4_Ne",
"material": "Ne",
"file": "Ne/huot_1991__C_eps_77.4_Ne.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 77.4
}
}
C_eps of Table I at 77.4 K, static (dielectric).
huot_1991/B_eps_242.95_Ne#
{
"id": "B_eps_242.95_Ne",
"material": "Ne",
"file": "Ne/huot_1991__B_eps_242.95_Ne.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 242.95
}
}
B_eps of Table I at 242.95 K, static (dielectric).
huot_1991/C_eps_242.95_Ne#
{
"id": "C_eps_242.95_Ne",
"material": "Ne",
"file": "Ne/huot_1991__C_eps_242.95_Ne.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 242.95
}
}
C_eps of Table I at 242.95 K, static (dielectric).
huot_1991/B_eps_323.15_Ne#
{
"id": "B_eps_323.15_Ne",
"material": "Ne",
"file": "Ne/huot_1991__B_eps_323.15_Ne.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 323.15
}
}
B_eps of Table I at 323.15 K, static (dielectric).
huot_1991/C_eps_323.15_Ne#
{
"id": "C_eps_323.15_Ne",
"material": "Ne",
"file": "Ne/huot_1991__C_eps_323.15_Ne.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 323.15
}
}
C_eps of Table I at 323.15 K, static (dielectric).
huot_1991/B_eps_242.95_Ar#
{
"id": "B_eps_242.95_Ar",
"material": "Ar",
"file": "Ar/huot_1991__B_eps_242.95_Ar.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 242.95
}
}
B_eps of Table I at 242.95 K, static (dielectric).
huot_1991/C_eps_242.95_Ar#
{
"id": "C_eps_242.95_Ar",
"material": "Ar",
"file": "Ar/huot_1991__C_eps_242.95_Ar.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 242.95
}
}
C_eps of Table I at 242.95 K, static (dielectric).
huot_1991/B_eps_303.15_Ar#
{
"id": "B_eps_303.15_Ar",
"material": "Ar",
"file": "Ar/huot_1991__B_eps_303.15_Ar.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 303.15
}
}
B_eps of Table I at 303.15 K, static (dielectric).
huot_1991/C_eps_303.15_Ar#
{
"id": "C_eps_303.15_Ar",
"material": "Ar",
"file": "Ar/huot_1991__C_eps_303.15_Ar.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 303.15
}
}
C_eps of Table I at 303.15 K, static (dielectric).
huot_1991/B_eps_407.6_Ar#
{
"id": "B_eps_407.6_Ar",
"material": "Ar",
"file": "Ar/huot_1991__B_eps_407.6_Ar.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 407.6
}
}
B_eps of Table I at 407.6 K, static (dielectric).
huot_1991/C_eps_407.6_Ar#
{
"id": "C_eps_407.6_Ar",
"material": "Ar",
"file": "Ar/huot_1991__C_eps_407.6_Ar.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 407.6
}
}
C_eps of Table I at 407.6 K, static (dielectric).
huot_1991/B_eps_242.95_Kr#
{
"id": "B_eps_242.95_Kr",
"material": "Kr",
"file": "Kr/huot_1991__B_eps_242.95_Kr.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 242.95
}
}
B_eps of Table I at 242.95 K, static (dielectric).
huot_1991/C_eps_242.95_Kr#
{
"id": "C_eps_242.95_Kr",
"material": "Kr",
"file": "Kr/huot_1991__C_eps_242.95_Kr.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 242.95
}
}
C_eps of Table I at 242.95 K, static (dielectric).
huot_1991/B_eps_323.15_Kr#
{
"id": "B_eps_323.15_Kr",
"material": "Kr",
"file": "Kr/huot_1991__B_eps_323.15_Kr.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 323.15
}
}
B_eps of Table I at 323.15 K, static (dielectric).
huot_1991/C_eps_323.15_Kr#
{
"id": "C_eps_323.15_Kr",
"material": "Kr",
"file": "Kr/huot_1991__C_eps_323.15_Kr.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 323.15
}
}
C_eps of Table I at 323.15 K, static (dielectric).
huot_1991/B_eps_407.6_Kr#
{
"id": "B_eps_407.6_Kr",
"material": "Kr",
"file": "Kr/huot_1991__B_eps_407.6_Kr.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 407.6
}
}
B_eps of Table I at 407.6 K, static (dielectric).
huot_1991/B_eps_242.95_Xe#
{
"id": "B_eps_242.95_Xe",
"material": "Xe",
"file": "Xe/huot_1991__B_eps_242.95_Xe.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 242.95
}
}
B_eps of Table I at 242.95 K, static (dielectric).
huot_1991/B_eps_323.15_Xe#
{
"id": "B_eps_323.15_Xe",
"material": "Xe",
"file": "Xe/huot_1991__B_eps_323.15_Xe.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 323.15
}
}
B_eps of Table I at 323.15 K, static (dielectric).
huot_1991/C_eps_323.15_Xe#
{
"id": "C_eps_323.15_Xe",
"material": "Xe",
"file": "Xe/huot_1991__C_eps_323.15_Xe.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 323.15
}
}
C_eps of Table I at 323.15 K, static (dielectric).
huot_1991/B_eps_407.6_Xe#
{
"id": "B_eps_407.6_Xe",
"material": "Xe",
"file": "Xe/huot_1991__B_eps_407.6_Xe.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm6/mol2",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 2,
"temperature_k": 407.6
}
}
B_eps of Table I at 407.6 K, static (dielectric).
huot_1991/C_eps_407.6_Xe#
{
"id": "C_eps_407.6_Xe",
"material": "Xe",
"file": "Xe/huot_1991__C_eps_407.6_Xe.csv",
"table": "tbl_9b08ee215279",
"quantity": "refractivity_virial_coefficient",
"unit": "cm9/mol3",
"abscissa_unit": "nm",
"wavelength_medium": "vacuum",
"use": "primary",
"uncertainty": {
"column": true,
"level": "not stated"
},
"parameters": {
"order": 3,
"temperature_k": 407.6
}
}
C_eps of Table I at 407.6 K, static (dielectric).
Formulas#
No formulas are recorded.
Corrections#
No dataset errata are recorded in this source record.
Formula corrections, where recorded, appear with their formulas above. Curation notes may also discuss corrections or unresolved interpretation. Consult the review register for the checks and decisions.