hunt_1984#

J. L. Hunt, J. D. Poll and L. Wolniewicz, “Ab initio calculation of properties of the neutral diatomic hydrogen molecules H2, HD, D2, HT, DT, and T2”, Can. J. Phys. 62, 1719 (1984)

Source record · Catalogue · Review register

DOI: 10.1139/p84-217

Source kind: theory

Recorded technique: Adiabatic calculation: the vibrational-rotational wave functions chi_vJ(R) of the adiabatic potential (Poll and Wolniewicz 1978, ref. 2), and the matrix elements <vJ|X|v’J’> = integral chi_vJ(R) X(R) chi_v’J’(R) dR (Eq. 1) of the clamped-nucleus quadrupole moment function Q(R) (ref. 2) and of the parallel and perpendicular polarizability functions alpha_par(R) and alpha_perp(R) of Kolos and Wolniewicz (1967, ref. 7 = kolos_1967), for H2, HD, D2, HT, DT and T2, v = 0-5 (p. 1719-1720). ‘Nonadiabatic contributions to these quantities are, therefore, expected to be quite small and we will not consider them here’ (p. 1719).

Materials in structured entries: D2, H2

Dataset quantities: raman_transition_polarizability

Contents: 68 datasets; 0 formulas.

Curation notes#

Journal pages 1719-1723 = PDF pages 1-5 (page n of the PDF is p. 1718 + n). Identity checked on the first page (the library’s VALIDATED_WITH_WARNINGS). Received 19 July 1984. Only H2 and D2 are curated materials; HD, HT, DT and T2 (the other four columns of every table) are not transcribed. H2 and D2 are single rovibrational levels here: no ortho:para mixture enters.

WHAT IS TAKEN. Tables 5-10 (pp. 1721-1723), the matrix elements of the parallel (Tables 5, 7, 9) and perpendicular (6, 8, 10) polarizability between the ground vibrational level (v = 0, J) and the level (v, J’) for v = 0-5: Delta J = 0 (Tables 5-6, J = 0-5), J’ = J + 2 (Tables 7-8, J = 0-3) and J’ = J - 2 (Tables 9-10, J = 2-5), ‘in atomic units’ (a0^3, e^2 a0^2/E_h). One dataset per table, gas and final v, one row per J (id <par|perp>_<dJ0|dJp2|dJm2>_v<v>_<gas>): 68 datasets, 320 values, raman_transition_polarizability with invariant parallel or perpendicular (the vocabulary’s component form). v = 0 of Tables 5-6 are the diagonal elements (the polarizability of the level); v = 0 of Tables 7-8 the pure rotational S(J) elements; v >= 1 the vibrational Raman Q, S and O lines of the v-0 bands. The overtones (v >= 2) are tabulated as compactly as the fundamentals and are kept; their small elements carry few significant digits.

STATIC. The paper does not say ‘static’, but its polarizability functions are Kolos and Wolniewicz’s 1967 static ones (kolos_1967: ‘Static only’), and its diagonal elements reproduce kolos_1967’s static per-level values (see CHECKED). Recorded with parameters.wavelength_nm = inf.

MEAN AND ANISOTROPY (for review): the invariants follow as alpha_mean = (alpha_par + 2 alpha_perp)/3 and gamma = alpha_par - alpha_perp of the same element (the Q-line strength needs both, an S or O line only gamma). Evaluated from the tables (scratch, 2026-09-27), a.u.: H2 Q(J) of the 1-0 band, J = 0-5: mean 0.73923, 0.74027, 0.74234, 0.74544, 0.74953, 0.75462; gamma 0.61001, 0.61175, 0.61524, 0.62049, 0.62741, 0.63612. D2 Q(J): mean 0.61633, 0.61677, 0.61765, 0.61898, 0.62075, 0.62294; gamma 0.50004, 0.50077, 0.50224, 0.50443, 0.50735, 0.51101. Pure rotational S(J), gamma of <0J|..|0J+2>, J = 0-3: H2 2.0351, 2.0500, 2.0725, 2.1025; D2 1.9639, 1.9713, 1.9825, 1.9974. 1-0 band S(J) gamma: H2 0.57081, 0.54630, 0.52323, 0.50152; D2 0.47749, 0.46313, 0.44943, 0.43633; O(J), J = 2-5: H2 0.65436, 0.68591, 0.71931, 0.75486; D2 0.52513, 0.54204, 0.56016, 0.57906.

CHECKED (2026-09-27): the diagonal elements (Tables 5-6, v = 0) give mean and anisotropy equal to kolos_1967’s static per-level Table III for J = 0-5 within one unit of the fourth decimal (H2 J = 0: 5.41380 and 2.0238 against 5.4139 and 2.0239; D2 J = 0: 5.34520 and 1.9584 against 5.3453 and 1.9584). rychlewski_1983’s Table VII (static column, H2 only, not extracted there) prints alpha_00,10 = 0.74006, gamma_00,10 = 0.61204, alpha_00,02 = 5.4304, gamma_00,02 = 2.0409: 0.11 %, 0.33 %, 0.06 % and 0.28 % above these (another polarizability function).

UNCERTAINTY: none is stated. ‘Comparison with experiment has shown that for these simple molecules the theoretical calculations are highly reliable’ (p. 1719) is general.

STRUCTURE (tools/extract/hunt_1984.py): every H2 and D2 cell was compared with the table images. Table 7’s v = 1 block is shifted one column in the library’s cells (the page prints ‘v J’ of its first row as ‘1 0’ with a stray mark); Table 5’s D2 column is headed ‘v_2’ in the cells. ERRATUM: Table 5 prints D2’s <00|alpha_par|20> as 0.05292, without a minus sign; the neighbouring J = 1-5 elements (-0.05304 ... -0.05478), every other v = 2 element of Tables 5-8 in all six columns, and the smooth J dependence show it is -0.05292 (corrected below).

NOT TAKEN (notes only): - Table 1 (p. 1720), the adiabatic dissociation energies D_vJ (cm-1) for v, J = 0-5 and the reduced masses (a.u.): H2 919.0764, D2 1835.2395. H2: D_00 = 36117.572, D_10 = 31955.529, D_01 = 35999.077; D2: D_00 = 36748.162, D_10 = 33754.207, D_01 = 36688.379. Differences give adiabatic level energies (H2: G(1) - G(0) = 4162.043 cm-1 for J = 0, F(1) - F(0) = 118.495; D2: 2993.955 and 59.783); nonadiabatic corrections are not included (the paper cites Wolniewicz 1983, ref. 1, for them). - Tables 2-4 (p. 1721), the quadrupole-moment elements <0J|Q|vJ>, <0J|Q|vJ+2>, <0J|Q|vJ-2> (a.u., with the footnote: ‘Many authors use a definition in which the quadrupole moment has half the size of the one used in this paper’, i.e. Q = R^2 - 2(3z^2 - r^2) summed as defined on p. 1719). H2 <00|Q|00> = 0.9671, <00|Q|10> = 0.1758; D2 0.9517 and 0.1478. No vocabulary quantity; not needed for Raman. - The ‘complete tables’ (v, v’ = 0-5, J = 0-5, total energies, <R^-2>) deposited with the Depository of Unpublished Data, NRC Canada (p. 1723): not in the library.

REPRODUCTIONS ELSEWHERE (not re-pointed: they are values computed from these, not reproduced datasets): mizrahi_1985_h2d2’s Table II quotes Hunt et al.’s H2 alpha_01,11 = 0.74027, gamma_01,11 = 0.61175 and D2 alpha_02,12 = 0.61765, gamma_02,12 = 0.50224 (a.u.): from Tables 5-6 H2 J = 1 (1.1481, 0.53635) and D2 J = 2 (0.95248, 0.45024) exactly. shelton_1987’s Table 2 (notes only there) prints H2 12.21 and 10.09, D2 10.18 and 8.28 (10^-42 C2 m2 J^-1): the same numbers times 1.64878e-41.

Recorded bibliographic identity status: VALIDATED_WITH_WARNINGS. This concerns identification of the source; it does not establish the scientific correctness of its contents.

Datasets#

hunt_1984/par_dJ0_v0_H2#

{
  "id": "par_dJ0_v0_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJ0_v0_H2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|0J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJ0_v1_H2#

{
  "id": "par_dJ0_v1_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJ0_v1_H2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|1J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJ0_v2_H2#

{
  "id": "par_dJ0_v2_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJ0_v2_H2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|2J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJ0_v3_H2#

{
  "id": "par_dJ0_v3_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJ0_v3_H2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|3J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJ0_v4_H2#

{
  "id": "par_dJ0_v4_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJ0_v4_H2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|4J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJ0_v5_H2#

{
  "id": "par_dJ0_v5_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJ0_v5_H2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|5J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJ0_v0_H2#

{
  "id": "perp_dJ0_v0_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJ0_v0_H2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 6 (p. 1722): <0J|alpha_perp|0J>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJ0_v1_H2#

{
  "id": "perp_dJ0_v1_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJ0_v1_H2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 6 (p. 1722): <0J|alpha_perp|1J>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJ0_v2_H2#

{
  "id": "perp_dJ0_v2_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJ0_v2_H2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 6 (p. 1722): <0J|alpha_perp|2J>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJ0_v3_H2#

{
  "id": "perp_dJ0_v3_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJ0_v3_H2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 6 (p. 1722): <0J|alpha_perp|3J>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJ0_v4_H2#

{
  "id": "perp_dJ0_v4_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJ0_v4_H2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 6 (p. 1722): <0J|alpha_perp|4J>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJ0_v5_H2#

{
  "id": "perp_dJ0_v5_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJ0_v5_H2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 6 (p. 1722): <0J|alpha_perp|5J>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJp2_v0_H2#

{
  "id": "par_dJp2_v0_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJp2_v0_H2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|0J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJp2_v1_H2#

{
  "id": "par_dJp2_v1_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJp2_v1_H2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|1J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJp2_v2_H2#

{
  "id": "par_dJp2_v2_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJp2_v2_H2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|2J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJp2_v3_H2#

{
  "id": "par_dJp2_v3_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJp2_v3_H2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|3J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJp2_v4_H2#

{
  "id": "par_dJp2_v4_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJp2_v4_H2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|4J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJp2_v5_H2#

{
  "id": "par_dJp2_v5_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJp2_v5_H2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|5J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJp2_v0_H2#

{
  "id": "perp_dJp2_v0_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJp2_v0_H2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 8 (p. 1722): <0J|alpha_perp|0J+2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJp2_v1_H2#

{
  "id": "perp_dJp2_v1_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJp2_v1_H2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 8 (p. 1722): <0J|alpha_perp|1J+2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJp2_v2_H2#

{
  "id": "perp_dJp2_v2_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJp2_v2_H2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 8 (p. 1722): <0J|alpha_perp|2J+2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJp2_v3_H2#

{
  "id": "perp_dJp2_v3_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJp2_v3_H2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 8 (p. 1722): <0J|alpha_perp|3J+2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJp2_v4_H2#

{
  "id": "perp_dJp2_v4_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJp2_v4_H2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 8 (p. 1722): <0J|alpha_perp|4J+2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJp2_v5_H2#

{
  "id": "perp_dJp2_v5_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJp2_v5_H2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 8 (p. 1722): <0J|alpha_perp|5J+2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJm2_v1_H2#

{
  "id": "par_dJm2_v1_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJm2_v1_H2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|1J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJm2_v2_H2#

{
  "id": "par_dJm2_v2_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJm2_v2_H2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|2J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJm2_v3_H2#

{
  "id": "par_dJm2_v3_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJm2_v3_H2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|3J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJm2_v4_H2#

{
  "id": "par_dJm2_v4_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJm2_v4_H2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|4J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJm2_v5_H2#

{
  "id": "par_dJm2_v5_H2",
  "material": "H2",
  "file": "H2/hunt_1984__par_dJm2_v5_H2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|5J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJm2_v1_H2#

{
  "id": "perp_dJm2_v1_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJm2_v1_H2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 10 (p. 1723): <0J|alpha_perp|1J-2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJm2_v2_H2#

{
  "id": "perp_dJm2_v2_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJm2_v2_H2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 10 (p. 1723): <0J|alpha_perp|2J-2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/perp_dJm2_v3_H2#

{
  "id": "perp_dJm2_v3_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJm2_v3_H2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 10 (p. 1723): <0J|alpha_perp|3J-2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJm2_v4_H2#

{
  "id": "perp_dJm2_v4_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJm2_v4_H2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 10 (p. 1723): <0J|alpha_perp|4J-2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/perp_dJm2_v5_H2#

{
  "id": "perp_dJm2_v5_H2",
  "material": "H2",
  "file": "H2/hunt_1984__perp_dJm2_v5_H2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Table 10 (p. 1723): <0J|alpha_perp|5J-2>, the perpendicular component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated. Small elements printed to 1e-5 a.u.: few significant digits.

hunt_1984/par_dJ0_v0_D2#

{
  "id": "par_dJ0_v0_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJ0_v0_D2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|0J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJ0_v1_D2#

{
  "id": "par_dJ0_v1_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJ0_v1_D2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|1J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJ0_v2_D2#

{
  "id": "par_dJ0_v2_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJ0_v2_D2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 5 (p. 1721): <0J|alpha_par|2J>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJ0_v3_D2#

{
  "id": "par_dJ0_v3_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJ0_v3_D2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJ0_v4_D2#

{
  "id": "par_dJ0_v4_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJ0_v4_D2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJ0_v5_D2#

{
  "id": "par_dJ0_v5_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJ0_v5_D2.csv",
  "table": "tbl_d342fdc7648a",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJ0_v0_D2#

{
  "id": "perp_dJ0_v0_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJ0_v0_D2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJ0_v1_D2#

{
  "id": "perp_dJ0_v1_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJ0_v1_D2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJ0_v2_D2#

{
  "id": "perp_dJ0_v2_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJ0_v2_D2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJ0_v3_D2#

{
  "id": "perp_dJ0_v3_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJ0_v3_D2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJ0_v4_D2#

{
  "id": "perp_dJ0_v4_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJ0_v4_D2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJ0_v5_D2#

{
  "id": "perp_dJ0_v5_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJ0_v5_D2.csv",
  "table": "tbl_67070dd33681",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJp2_v0_D2#

{
  "id": "par_dJp2_v0_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJp2_v0_D2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|0J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJp2_v1_D2#

{
  "id": "par_dJp2_v1_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJp2_v1_D2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|1J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJp2_v2_D2#

{
  "id": "par_dJp2_v2_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJp2_v2_D2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 7 (p. 1722): <0J|alpha_par|2J+2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 0-3 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJp2_v3_D2#

{
  "id": "par_dJp2_v3_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJp2_v3_D2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJp2_v4_D2#

{
  "id": "par_dJp2_v4_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJp2_v4_D2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJp2_v5_D2#

{
  "id": "par_dJp2_v5_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJp2_v5_D2.csv",
  "table": "tbl_96e803fab9c9",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJp2_v0_D2#

{
  "id": "perp_dJp2_v0_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJp2_v0_D2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJp2_v1_D2#

{
  "id": "perp_dJp2_v1_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJp2_v1_D2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJp2_v2_D2#

{
  "id": "perp_dJp2_v2_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJp2_v2_D2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJp2_v3_D2#

{
  "id": "perp_dJp2_v3_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJp2_v3_D2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJp2_v4_D2#

{
  "id": "perp_dJp2_v4_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJp2_v4_D2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJp2_v5_D2#

{
  "id": "perp_dJp2_v5_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJp2_v5_D2.csv",
  "table": "tbl_9fd840e5f3aa",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJm2_v1_D2#

{
  "id": "par_dJm2_v1_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJm2_v1_D2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|1J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJm2_v2_D2#

{
  "id": "par_dJm2_v2_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJm2_v2_D2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

Table 9 (p. 1722): <0J|alpha_par|2J-2>, the parallel component of the static polarizability (Kolos and Wolniewicz’s functions), atomic units, J = 2-5 (the row), adiabatic; no uncertainty stated.

hunt_1984/par_dJm2_v3_D2#

{
  "id": "par_dJm2_v3_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJm2_v3_D2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJm2_v4_D2#

{
  "id": "par_dJm2_v4_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJm2_v4_D2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/par_dJm2_v5_D2#

{
  "id": "par_dJm2_v5_D2",
  "material": "D2",
  "file": "D2/hunt_1984__par_dJm2_v5_D2.csv",
  "table": "tbl_69944584e92c",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)",
    "invariant": "parallel",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJm2_v1_D2#

{
  "id": "perp_dJm2_v1_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJm2_v1_D2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJm2_v2_D2#

{
  "id": "perp_dJm2_v2_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJm2_v2_D2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJm2_v3_D2#

{
  "id": "perp_dJm2_v3_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJm2_v3_D2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJm2_v4_D2#

{
  "id": "perp_dJm2_v4_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJm2_v4_D2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

hunt_1984/perp_dJm2_v5_D2#

{
  "id": "perp_dJm2_v5_D2",
  "material": "D2",
  "file": "D2/hunt_1984__perp_dJm2_v5_D2.csv",
  "table": "tbl_62b45dba2e04",
  "quantity": "raman_transition_polarizability",
  "unit": "au",
  "abscissa": "label",
  "use": "primary",
  "parameters": {
    "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)",
    "invariant": "perpendicular",
    "wavelength_nm": Infinity
  }
}

Formulas#

No formulas are recorded.

Corrections#

[
  {
    "dataset": "par_dJ0_v2_D2",
    "row": "J=0",
    "column": "value",
    "printed": "0.05292",
    "corrected": "-0.05292",
    "reason": "Table 5 prints D2's <00|alpha_par|20> without its minus sign.",
    "evidence": "The table image (tbl_d342fdc7648a, p. 1721) shows 0.05292 unsigned. The D2 elements of the same block for J = 1-5 are -0.05304, -0.05329, -0.05366, -0.05416, -0.05478 (a smooth J dependence that continues to J = 0 at about -0.0529); every other v = 2 element of Tables 5-8, in all six isotopologue columns, is negative (HD -0.06692, HT -0.06248, DT -0.04773 in the same row); and D2's perpendicular element <00|alpha_perp|20> is -0.04662 (Table 6). Checked 2026-09-27."
  }
]

Formula corrections, where recorded, appear with their formulas above. Curation notes may also discuss corrections or unresolved interpretation. Consult the review register for the checks and decisions.