hunt_1984 ========= J\. L\. Hunt, J\. D\. Poll and L\. Wolniewicz, "Ab initio calculation of properties of the neutral diatomic hydrogen molecules H2, HD, D2, HT, DT, and T2", Can\. J\. Phys\. 62, 1719 \(1984\) `Source record `__ · :doc:`Catalogue ` · :doc:`Review register ` DOI: `10\.1139/p84\-217 `__ **Source kind:** theory **Recorded technique:** Adiabatic calculation\: the vibrational\-rotational wave functions chi\_vJ\(R\) of the adiabatic potential \(Poll and Wolniewicz 1978, ref\. 2\), and the matrix elements \ = integral chi\_vJ\(R\) X\(R\) chi\_v'J'\(R\) dR \(Eq\. 1\) of the clamped\-nucleus quadrupole moment function Q\(R\) \(ref\. 2\) and of the parallel and perpendicular polarizability functions alpha\_par\(R\) and alpha\_perp\(R\) of Kolos and Wolniewicz \(1967, ref\. 7 = kolos\_1967\), for H2, HD, D2, HT, DT and T2, v = 0\-5 \(p\. 1719\-1720\)\. 'Nonadiabatic contributions to these quantities are, therefore, expected to be quite small and we will not consider them here' \(p\. 1719\)\. **Materials in structured entries:** D2, H2 **Dataset quantities:** raman\_transition\_polarizability **Contents:** 68 datasets; 0 formulas. Curation notes -------------- Journal pages 1719\-1723 = PDF pages 1\-5 \(page n of the PDF is p\. 1718 \+ n\)\. Identity checked on the first page \(the library's VALIDATED\_WITH\_WARNINGS\)\. Received 19 July 1984\. Only H2 and D2 are curated materials; HD, HT, DT and T2 \(the other four columns of every table\) are not transcribed\. H2 and D2 are single rovibrational levels here\: no ortho\:para mixture enters\. WHAT IS TAKEN\. Tables 5\-10 \(pp\. 1721\-1723\), the matrix elements of the parallel \(Tables 5, 7, 9\) and perpendicular \(6, 8, 10\) polarizability between the ground vibrational level \(v = 0, J\) and the level \(v, J'\) for v = 0\-5\: Delta J = 0 \(Tables 5\-6, J = 0\-5\), J' = J \+ 2 \(Tables 7\-8, J = 0\-3\) and J' = J \- 2 \(Tables 9\-10, J = 2\-5\), 'in atomic units' \(a0^3, e^2 a0^2/E\_h\)\. One dataset per table, gas and final v, one row per J \(id \\_\\_v\\_\\)\: 68 datasets, 320 values, raman\_transition\_polarizability with invariant parallel or perpendicular \(the vocabulary's component form\)\. v = 0 of Tables 5\-6 are the diagonal elements \(the polarizability of the level\); v = 0 of Tables 7\-8 the pure rotational S\(J\) elements; v \>= 1 the vibrational Raman Q, S and O lines of the v\-0 bands\. The overtones \(v \>= 2\) are tabulated as compactly as the fundamentals and are kept; their small elements carry few significant digits\. STATIC\. The paper does not say 'static', but its polarizability functions are Kolos and Wolniewicz's 1967 static ones \(kolos\_1967\: 'Static only'\), and its diagonal elements reproduce kolos\_1967's static per\-level values \(see CHECKED\)\. Recorded with parameters\.wavelength\_nm = inf\. MEAN AND ANISOTROPY \(for review\)\: the invariants follow as alpha\_mean = \(alpha\_par \+ 2 alpha\_perp\)/3 and gamma = alpha\_par \- alpha\_perp of the same element \(the Q\-line strength needs both, an S or O line only gamma\)\. Evaluated from the tables \(scratch, 2026\-09\-27\), a\.u\.\: H2 Q\(J\) of the 1\-0 band, J = 0\-5\: mean 0\.73923, 0\.74027, 0\.74234, 0\.74544, 0\.74953, 0\.75462; gamma 0\.61001, 0\.61175, 0\.61524, 0\.62049, 0\.62741, 0\.63612\. D2 Q\(J\)\: mean 0\.61633, 0\.61677, 0\.61765, 0\.61898, 0\.62075, 0\.62294; gamma 0\.50004, 0\.50077, 0\.50224, 0\.50443, 0\.50735, 0\.51101\. Pure rotational S\(J\), gamma of \<0J\|\.\.\|0J\+2\>, J = 0\-3\: H2 2\.0351, 2\.0500, 2\.0725, 2\.1025; D2 1\.9639, 1\.9713, 1\.9825, 1\.9974\. 1\-0 band S\(J\) gamma\: H2 0\.57081, 0\.54630, 0\.52323, 0\.50152; D2 0\.47749, 0\.46313, 0\.44943, 0\.43633; O\(J\), J = 2\-5\: H2 0\.65436, 0\.68591, 0\.71931, 0\.75486; D2 0\.52513, 0\.54204, 0\.56016, 0\.57906\. CHECKED \(2026\-09\-27\)\: the diagonal elements \(Tables 5\-6, v = 0\) give mean and anisotropy equal to kolos\_1967's static per\-level Table III for J = 0\-5 within one unit of the fourth decimal \(H2 J = 0\: 5\.41380 and 2\.0238 against 5\.4139 and 2\.0239; D2 J = 0\: 5\.34520 and 1\.9584 against 5\.3453 and 1\.9584\)\. rychlewski\_1983's Table VII \(static column, H2 only, not extracted there\) prints alpha\_00,10 = 0\.74006, gamma\_00,10 = 0\.61204, alpha\_00,02 = 5\.4304, gamma\_00,02 = 2\.0409\: 0\.11 %, 0\.33 %, 0\.06 % and 0\.28 % above these \(another polarizability function\)\. UNCERTAINTY\: none is stated\. 'Comparison with experiment has shown that for these simple molecules the theoretical calculations are highly reliable' \(p\. 1719\) is general\. STRUCTURE \(tools/extract/hunt\_1984\.py\)\: every H2 and D2 cell was compared with the table images\. Table 7's v = 1 block is shifted one column in the library's cells \(the page prints 'v J' of its first row as '1 0' with a stray mark\); Table 5's D2 column is headed 'v\_2' in the cells\. ERRATUM\: Table 5 prints D2's \<00\|alpha\_par\|20\> as 0\.05292, without a minus sign; the neighbouring J = 1\-5 elements \(\-0\.05304 \.\.\. \-0\.05478\), every other v = 2 element of Tables 5\-8 in all six columns, and the smooth J dependence show it is \-0\.05292 \(corrected below\)\. NOT TAKEN \(notes only\)\: \- Table 1 \(p\. 1720\), the adiabatic dissociation energies D\_vJ \(cm\-1\) for v, J = 0\-5 and the reduced masses \(a\.u\.\)\: H2 919\.0764, D2 1835\.2395\. H2\: D\_00 = 36117\.572, D\_10 = 31955\.529, D\_01 = 35999\.077; D2\: D\_00 = 36748\.162, D\_10 = 33754\.207, D\_01 = 36688\.379\. Differences give adiabatic level energies \(H2\: G\(1\) \- G\(0\) = 4162\.043 cm\-1 for J = 0, F\(1\) \- F\(0\) = 118\.495; D2\: 2993\.955 and 59\.783\); nonadiabatic corrections are not included \(the paper cites Wolniewicz 1983, ref\. 1, for them\)\. \- Tables 2\-4 \(p\. 1721\), the quadrupole\-moment elements \<0J\|Q\|vJ\>, \<0J\|Q\|vJ\+2\>, \<0J\|Q\|vJ\-2\> \(a\.u\., with the footnote\: 'Many authors use a definition in which the quadrupole moment has half the size of the one used in this paper', i\.e\. Q = R^2 \- 2\(3z^2 \- r^2\) summed as defined on p\. 1719\)\. H2 \<00\|Q\|00\> = 0\.9671, \<00\|Q\|10\> = 0\.1758; D2 0\.9517 and 0\.1478\. No vocabulary quantity; not needed for Raman\. \- The 'complete tables' \(v, v' = 0\-5, J = 0\-5, total energies, \\) deposited with the Depository of Unpublished Data, NRC Canada \(p\. 1723\)\: not in the library\. REPRODUCTIONS ELSEWHERE \(not re\-pointed\: they are values computed from these, not reproduced datasets\)\: mizrahi\_1985\_h2d2's Table II quotes Hunt et al\.'s H2 alpha\_01,11 = 0\.74027, gamma\_01,11 = 0\.61175 and D2 alpha\_02,12 = 0\.61765, gamma\_02,12 = 0\.50224 \(a\.u\.\)\: from Tables 5\-6 H2 J = 1 \(1\.1481, 0\.53635\) and D2 J = 2 \(0\.95248, 0\.45024\) exactly\. shelton\_1987's Table 2 \(notes only there\) prints H2 12\.21 and 10\.09, D2 10\.18 and 8\.28 \(10^\-42 C2 m2 J^\-1\)\: the same numbers times 1\.64878e\-41\. **Recorded bibliographic identity status:** VALIDATED\_WITH\_WARNINGS. This concerns identification of the source; it does not establish the scientific correctness of its contents. Datasets -------- hunt\_1984/par\_dJ0\_v0\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v0_H2", "material": "H2", "file": "H2/hunt_1984__par_dJ0_v0_H2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|0J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJ0\_v1\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v1_H2", "material": "H2", "file": "H2/hunt_1984__par_dJ0_v1_H2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|1J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJ0\_v2\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v2_H2", "material": "H2", "file": "H2/hunt_1984__par_dJ0_v2_H2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|2J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJ0\_v3\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v3_H2", "material": "H2", "file": "H2/hunt_1984__par_dJ0_v3_H2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|3J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJ0\_v4\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v4_H2", "material": "H2", "file": "H2/hunt_1984__par_dJ0_v4_H2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|4J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJ0\_v5\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v5_H2", "material": "H2", "file": "H2/hunt_1984__par_dJ0_v5_H2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|5J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJ0\_v0\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v0_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJ0_v0_H2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|0J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJ0\_v1\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v1_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJ0_v1_H2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|1J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJ0\_v2\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v2_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJ0_v2_H2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|2J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJ0\_v3\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v3_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJ0_v3_H2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|3J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJ0\_v4\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v4_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJ0_v4_H2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|4J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJ0\_v5\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v5_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJ0_v5_H2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|5J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJp2\_v0\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v0_H2", "material": "H2", "file": "H2/hunt_1984__par_dJp2_v0_H2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|0J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJp2\_v1\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v1_H2", "material": "H2", "file": "H2/hunt_1984__par_dJp2_v1_H2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|1J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJp2\_v2\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v2_H2", "material": "H2", "file": "H2/hunt_1984__par_dJp2_v2_H2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|2J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJp2\_v3\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v3_H2", "material": "H2", "file": "H2/hunt_1984__par_dJp2_v3_H2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|3J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJp2\_v4\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v4_H2", "material": "H2", "file": "H2/hunt_1984__par_dJp2_v4_H2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|4J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJp2\_v5\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v5_H2", "material": "H2", "file": "H2/hunt_1984__par_dJp2_v5_H2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|5J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJp2\_v0\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v0_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJp2_v0_H2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|0J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJp2\_v1\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v1_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJp2_v1_H2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|1J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJp2\_v2\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v2_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJp2_v2_H2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|2J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJp2\_v3\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v3_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJp2_v3_H2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|3J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJp2\_v4\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v4_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJp2_v4_H2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|4J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJp2\_v5\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v5_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJp2_v5_H2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|5J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJm2\_v1\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v1_H2", "material": "H2", "file": "H2/hunt_1984__par_dJm2_v1_H2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|1J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJm2\_v2\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v2_H2", "material": "H2", "file": "H2/hunt_1984__par_dJm2_v2_H2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|2J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJm2\_v3\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v3_H2", "material": "H2", "file": "H2/hunt_1984__par_dJm2_v3_H2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|3J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJm2\_v4\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v4_H2", "material": "H2", "file": "H2/hunt_1984__par_dJm2_v4_H2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|4J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJm2\_v5\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v5_H2", "material": "H2", "file": "H2/hunt_1984__par_dJm2_v5_H2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|5J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJm2\_v1\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v1_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJm2_v1_H2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|1J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJm2\_v2\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v2_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJm2_v2_H2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|2J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJm2\_v3\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v3_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJm2_v3_H2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|3J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJm2\_v4\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v4_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJm2_v4_H2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|4J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJm2\_v5\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v5_H2", "material": "H2", "file": "H2/hunt_1984__perp_dJm2_v5_H2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|5J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJ0\_v0\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v0_D2", "material": "D2", "file": "D2/hunt_1984__par_dJ0_v0_D2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|0J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJ0\_v1\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v1_D2", "material": "D2", "file": "D2/hunt_1984__par_dJ0_v1_D2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|1J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJ0\_v2\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v2_D2", "material": "D2", "file": "D2/hunt_1984__par_dJ0_v2_D2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|2J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJ0\_v3\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v3_D2", "material": "D2", "file": "D2/hunt_1984__par_dJ0_v3_D2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|3J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJ0\_v4\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v4_D2", "material": "D2", "file": "D2/hunt_1984__par_dJ0_v4_D2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|4J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJ0\_v5\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJ0_v5_D2", "material": "D2", "file": "D2/hunt_1984__par_dJ0_v5_D2.csv", "table": "tbl_d342fdc7648a", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 5 \(p\. 1721\)\: \<0J\|alpha\_par\|5J\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJ0\_v0\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v0_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJ0_v0_D2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J (the expectation value in level (0, J); per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|0J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJ0\_v1\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v1_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJ0_v1_D2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J (Q(J) of the 1-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|1J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJ0\_v2\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v2_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJ0_v2_D2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J (Q(J) of the 2-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|2J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJ0\_v3\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v3_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJ0_v3_D2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J (Q(J) of the 3-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|3J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJ0\_v4\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v4_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJ0_v4_D2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J (Q(J) of the 4-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|4J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJ0\_v5\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJ0_v5_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJ0_v5_D2.csv", "table": "tbl_67070dd33681", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J (Q(J) of the 5-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 6 \(p\. 1722\)\: \<0J\|alpha\_perp\|5J\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJp2\_v0\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v0_D2", "material": "D2", "file": "D2/hunt_1984__par_dJp2_v0_D2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|0J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJp2\_v1\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v1_D2", "material": "D2", "file": "D2/hunt_1984__par_dJp2_v1_D2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|1J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJp2\_v2\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v2_D2", "material": "D2", "file": "D2/hunt_1984__par_dJp2_v2_D2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|2J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJp2\_v3\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v3_D2", "material": "D2", "file": "D2/hunt_1984__par_dJp2_v3_D2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|3J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJp2\_v4\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v4_D2", "material": "D2", "file": "D2/hunt_1984__par_dJp2_v4_D2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|4J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJp2\_v5\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJp2_v5_D2", "material": "D2", "file": "D2/hunt_1984__par_dJp2_v5_D2.csv", "table": "tbl_96e803fab9c9", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 7 \(p\. 1722\)\: \<0J\|alpha\_par\|5J\+2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJp2\_v0\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v0_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJp2_v0_D2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=0,J+2 (pure rotational S(J); per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|0J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJp2\_v1\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v1_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJp2_v1_D2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J+2 (S(J) of the 1-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|1J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJp2\_v2\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v2_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJp2_v2_D2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J+2 (S(J) of the 2-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|2J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJp2\_v3\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v3_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJp2_v3_D2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J+2 (S(J) of the 3-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|3J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJp2\_v4\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v4_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJp2_v4_D2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J+2 (S(J) of the 4-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|4J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJp2\_v5\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJp2_v5_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJp2_v5_D2.csv", "table": "tbl_9fd840e5f3aa", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J+2 (S(J) of the 5-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 8 \(p\. 1722\)\: \<0J\|alpha\_perp\|5J\+2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 0\-3 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJm2\_v1\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v1_D2", "material": "D2", "file": "D2/hunt_1984__par_dJm2_v1_D2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|1J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJm2\_v2\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v2_D2", "material": "D2", "file": "D2/hunt_1984__par_dJm2_v2_D2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|2J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/par\_dJm2\_v3\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v3_D2", "material": "D2", "file": "D2/hunt_1984__par_dJm2_v3_D2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|3J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJm2\_v4\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v4_D2", "material": "D2", "file": "D2/hunt_1984__par_dJm2_v4_D2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|4J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/par\_dJm2\_v5\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "par_dJm2_v5_D2", "material": "D2", "file": "D2/hunt_1984__par_dJm2_v5_D2.csv", "table": "tbl_69944584e92c", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)", "invariant": "parallel", "wavelength_nm": Infinity } } Table 9 \(p\. 1722\)\: \<0J\|alpha\_par\|5J\-2\>, the parallel component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJm2\_v1\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v1_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJm2_v1_D2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=1,J-2 (O(J) of the 1-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|1J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJm2\_v2\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v2_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJm2_v2_D2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=2,J-2 (O(J) of the 2-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|2J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. hunt\_1984/perp\_dJm2\_v3\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v3_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJm2_v3_D2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=3,J-2 (O(J) of the 3-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|3J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJm2\_v4\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v4_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJm2_v4_D2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=4,J-2 (O(J) of the 4-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|4J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. hunt\_1984/perp\_dJm2\_v5\_D2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "perp_dJm2_v5_D2", "material": "D2", "file": "D2/hunt_1984__perp_dJm2_v5_D2.csv", "table": "tbl_62b45dba2e04", "quantity": "raman_transition_polarizability", "unit": "au", "abscissa": "label", "use": "primary", "parameters": { "transition": "v=0,J -> v=5,J-2 (O(J) of the 5-0 band; per row: J)", "invariant": "perpendicular", "wavelength_nm": Infinity } } Table 10 \(p\. 1723\)\: \<0J\|alpha\_perp\|5J\-2\>, the perpendicular component of the static polarizability \(Kolos and Wolniewicz's functions\), atomic units, J = 2\-5 \(the row\), adiabatic; no uncertainty stated\. Small elements printed to 1e\-5 a\.u\.\: few significant digits\. Formulas -------- No formulas are recorded. Corrections ----------- .. code-block:: text [ { "dataset": "par_dJ0_v2_D2", "row": "J=0", "column": "value", "printed": "0.05292", "corrected": "-0.05292", "reason": "Table 5 prints D2's <00|alpha_par|20> without its minus sign.", "evidence": "The table image (tbl_d342fdc7648a, p. 1721) shows 0.05292 unsigned. The D2 elements of the same block for J = 1-5 are -0.05304, -0.05329, -0.05366, -0.05416, -0.05478 (a smooth J dependence that continues to J = 0 at about -0.0529); every other v = 2 element of Tables 5-8, in all six isotopologue columns, is negative (HD -0.06692, HT -0.06248, DT -0.04773 in the same row); and D2's perpendicular element <00|alpha_perp|20> is -0.04662 (Table 6). Checked 2026-09-27." } ] Formula corrections, where recorded, appear with their formulas above. Curation notes may also discuss corrections or unresolved interpretation. Consult the :doc:`review register ` for the checks and decisions.