serdyuchenko_2014 ================= A\. Serdyuchenko, V\. Gorshelev, M\. Weber, W\. Chehade and J\. P\. Burrows, "High spectral resolution ozone absorption cross\-sections \- Part 2\: Temperature dependence", Atmos\. Meas\. Tech\. 7, 625 \(2014\) `Source record `__ · :doc:`Catalogue ` · :doc:`Review register ` DOI: `10\.5194/amt\-7\-625\-2014 `__ **Source kind:** measurement **Recorded technique:** The setup of gorshelev\_2014 \(Part 1\) at eleven temperatures, 293 K down to 193 K in 10 K steps\: echelle \(213\-310 and 350\-450 nm, 0\.02 nm\) and FTS \(1 cm^\-1; 2 cm^\-1 in 780\-1100 nm\); absolute measurements with pure O3 at 310\-335 and 450\-780 nm \(FTS, 1 cm^\-1\), calibrated 'individually at each temperature', the relative spectra \(O2/O3 flow, pre\-cooled through a passivated 10 m copper coil\) scaled and concatenated to them per temperature; Haake cryostats \(fluctuations below \+\-0\.3 K\); the gas temperature checked by the O2 A\-band rotational temperature \(HITRAN 2008 line parameters\), agreeing with the Pt and cryostat sensors within 1\-3 K \(pp\. 626\-627\)\. **Materials in structured entries:** O3 **Dataset quantities:** absorption\_cross\_section **Contents:** 6 datasets; 0 formulas. Curation notes -------------- Identity checked against the first page \(PDF page 1, journal p\. 625\)\: Serdyuchenko, Gorshelev, Weber, Chehade and Burrows, Atmos\. Meas\. Tech\. 7, 625\-636 \(2014\), Part 2 \(temperature dependence; Part 1 is gorshelev\_2014\)\. Journal pages 625\-636 = PDF pages 1\-12\. O3 only\. Facts for the data files \(the Bremen 'Serdyuchenko/Gorshelev' set, the model's primary absorption term\)\: \- Temperatures\: 293, 283, \.\.\., 193 K \(eleven, 10 K steps\) \(abstract, p\. 627\)\. \- Resolution\: '0\.02\-0\.24 nm \(full width at half maximum, FWHM\)' \(abstract\); echelle 0\.02 nm in 213\-450 nm; FTS 1 and 2 cm^\-1 \(p\. 627\); details, sampling and the 0\.01 nm interpolated grid in gorshelev\_2014\. \- Wavelengths\: VACUUM \(gorshelev\_2014\: echelle air wavelengths converted with Edlen 1966, FTS wavenumbers\); here too the comparison data were 'converted to vacuum wavelength' \(p\. 631\)\. \- Absolute scale\: pure\-O3 pressure at each temperature separately \(310\-335 and 450\-780 nm\), 'independent for every temperature and free from uncertainties of previous studies' \(p\. 627\); the O3 decay matters only above 243 K\. \- Uncertainty \(Table 2, image checked, p\. 628\)\: systematic below 1\.2\-2\.6 % 'depending on temperature' \(pressure sensors 0\.5 %, temperature measurements below 0\.3\-1\.6 % \(1\-3 K\), temperature non\-uniformity below 0\.3 %, cell length below 0\.04\-0\.07 %, leaks below 0\.1 %, O2 impurity 0\.005 %\); statistical below 1\-2\.2 % 'depending on spectral region' \(ozone decay below 1 %, light source 0\.2 % \(vis\) / 2 % \(UV\), pressure below 0\.08 %, temperature below 0\.1\-0\.16 %\)\. 'A relative uncertainty of 1\.5 % can be taken as the upper limit for the temperature\-related uncertainty' \(p\. 627\); 'in the spectral regions with weak absorption \(350\-450 nm and longer than 900 nm\) statistical uncertainty can reach up to 30 %' \(p\. 627\)\. Levels not stated\. \- The published file\: 'available on the homepage of the Molecular Spectroscopy Laboratory of the Institute of the Environmental Physics, University of Bremen \.\.\. Cross\-section updates from future measurements are expected' \(p\. 635\)\: the version fetched must be named \(TC\-189\)\. Temperature parametrisation \(p\. 630\)\: Eq\. \(1\), sigma\(lambda\) = 10^\-20 \[C0\(lambda\) \+ C1\(lambda\) T \+ C2\(lambda\) T^2\], T in degrees Celsius, cm^2 molecule^\-1, fitted per wavelength \(the Bass\-Paur form\); it reproduces the Huggins\-band data 'to within 1\.5 %' at most wavelengths and generally within 2 % at 193 and 293 K\. The coefficients are not printed \(a data product, not a formula entry\)\. Temperature effects \(pp\. 629\-634\)\: the Hartley band's Gaussian centre moves 0\.14 nm from 203 to 293 K \(BP 0\.18, Bogumil 0\.05, BMD 0\.36 nm from 218 to 295 K\); about 2 % increase at the Hartley maximum over 293\-193 K; about 1 % near 600 nm over 193\-293 K, increasing as the temperature falls; a clear temperature dependence in the Wulf band\. Band\-integrated cross sections \(Table 3, image checked, p\. 629; cm^2 molecule^\-1 nm, columns 295 \+\- 3, 273 \+\- 3, 243 \+\- 3, 221 \+\- 3 and 203 \+\- 1 K; ratios to this work in brackets\)\: this work, Hartley 245\-340 nm \(x 10^\-16\) 3\.53, 3\.53, 3\.53, 3\.54, 3\.52; Huggins 325\-340 nm \(x 10^\-20\) 8\.29, 7\.41, 6\.28, 5\.77, 5\.46; Chappuis 410\-690 nm \(x 10^\-19\) 6\.22, 6\.2, 6\.16, 6\.15, 6\.13; Wulf 663\-1000 nm \(x 10^\-19\) 1\.040, 1\.030, 1\.009, 1\.003, 0\.988\. The table also gives BMD, Paur and Bass, Guer et al\. \(2005\), Chehade et al\. \(2013\), Bogumil et al\. \(2003\), Burrows et al\. \(1999\) and Orphal \(2003\) \(tables/ tbl\_41ebb553ca3e\.json\)\. Not extracted\: no vocabulary quantity for a cross section integrated over wavelength \(format need\)\. The Wulf limits here are 663\-1000 nm \(the text of both papers\), against 633\-1000 nm in gorshelev\_2014's Table 3\. Datasets\: Table 4 \(image checked, p\. 634\), 'x 10^\-22 cm^2 molecule^\-1', at vacuum wavelengths 'taken from El Helou et al\. \(2005\)', one per column with its temperature\. 'This work' at 223 K\: points of the 223 K file, 'check'\. Burkholder and Talukdar's 779\.416 nm value, 1\.541, is half every other value there \(3\.15\-3\.33\) and lies outside their range 407\-762 nm \(Table 1\)\: suspect, kept as printed \(TC\-189\)\. **Recorded bibliographic identity status:** VALIDATED. This concerns identification of the source; it does not establish the scientific correctness of its contents. Datasets -------- serdyuchenko\_2014/this\_work\_223 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "this_work_223", "material": "O3", "file": "O3/serdyuchenko_2014__this_work_223.csv", "table": "tbl_75e505961474", "quantity": "absorption_cross_section", "unit": "cm2", "scale": 1e-22, "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "check", "uncertainty": { "relative": 0.03, "level": "not stated", "relative_rows": { "944.259": 0.3, "991.841": 0.3, "1046.766": 0.3 } }, "parameters": { "temperature_k": 223.0 } } Table 4 'This work, 223 K'\: 13 wavelengths 543\.667\-1046\.766 nm\. About 3 % \(Table 2\: systematic below 1\.2\-2\.6 %, statistical below 1\-2\.2 %\); 'up to 30 %' beyond 900 nm \(p\. 627\), used for 944\.259\-1046\.766 nm\. Level not stated\. serdyuchenko\_2014/el\_helou\_2005\_223 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "el_helou_2005_223", "material": "O3", "file": "O3/serdyuchenko_2014__el_helou_2005_223.csv", "table": "tbl_75e505961474", "quantity": "absorption_cross_section", "unit": "cm2", "scale": 1e-22, "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "El Helou, Z., Churassy, S., Wannous, G., Bacis, R., and Boursey, E.: Absolute cross sections of ozone at atmospheric temperatures for the Wulf and the Chappuis bands, J. Chem. Phys., 122, 244311, 2005" ], "parameters": { "temperature_k": 222.5 } } Table 4 'El Helou et al\. \(2005\), 222\-223 K' \(the temperature recorded as 222\.5 K, the middle of the printed range\)\: 10 wavelengths to 898\.247 nm\. serdyuchenko\_2014/el\_helou\_2005\_150 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "el_helou_2005_150", "material": "O3", "file": "O3/serdyuchenko_2014__el_helou_2005_150.csv", "table": "tbl_75e505961474", "quantity": "absorption_cross_section", "unit": "cm2", "scale": 1e-22, "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "El Helou, Z., Churassy, S., Wannous, G., Bacis, R., and Boursey, E.: Absolute cross sections of ozone at atmospheric temperatures for the Wulf and the Chappuis bands, J. Chem. Phys., 122, 244311, 2005" ], "parameters": { "temperature_k": 150.0 } } Table 4 'El Helou et al\. \(2005\), 150 K'\: 8 wavelengths 748\.721\-1046\.766 nm; 'only slightly different from those at 223 K' \(p\. 634\)\. serdyuchenko\_2014/burkholder\_talukdar\_1994\_220 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "burkholder_talukdar_1994_220", "material": "O3", "file": "O3/serdyuchenko_2014__burkholder_talukdar_1994_220.csv", "table": "tbl_75e505961474", "quantity": "absorption_cross_section", "unit": "cm2", "scale": 1e-22, "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "Burkholder, J. B. and Talukdar, R. K.: Temperature dependence of the ozone absorption spectrum over the wavelength range 410-760 nm, Geophys. Res. Lett., 21, 581-584, 1994" ], "parameters": { "temperature_k": 220.0 } } Table 4 'Burkholder and Talukdar \(1994\), 220 K'\: 7 wavelengths; normalised to Anderson and Mauersberger \(1992\) \(p\. 626\)\. The 779\.416 nm value 1\.541 is suspect \(source notes\)\. serdyuchenko\_2014/bogumil\_2003\_223 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "bogumil_2003_223", "material": "O3", "file": "O3/serdyuchenko_2014__bogumil_2003_223.csv", "table": "tbl_75e505961474", "quantity": "absorption_cross_section", "unit": "cm2", "scale": 1e-22, "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "Bogumil, K., Orphal, J., Homann, T., Voigt, S., Spietz, P., Fleischmann, O. C., Vogel, A., Hartmann, M., Bovensmann, H., Frerick, J., and Burrows, J. P.: Measurements of molecular absorption spectra with the SCIAMACHY pre-flight model: instrument characterization and reference data for atmospheric remote-sensing in the 230-2380 nm region, J. Photoch. Photobiol. A., 157, 157-167, 2003" ], "parameters": { "temperature_k": 223.0 } } Table 4 'Bogumil et al\. \(2003\), 223 K'\: 13 wavelengths\. serdyuchenko\_2014/bmd\_218 ~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "bmd_218", "material": "O3", "file": "O3/serdyuchenko_2014__bmd_218.csv", "table": "tbl_75e505961474", "quantity": "absorption_cross_section", "unit": "cm2", "scale": 1e-22, "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "brion_1998" ], "parameters": { "temperature_k": 218.0 } } Table 4 'BMD, Brion et al\. \(1993, 1998\), Malicet et al\. \(1989, 1995\), 218 K'\: 5 visible wavelengths \(543\.667\-632\.991 nm\), the 218 K Chappuis data of brion\_1998 \(515\-650 nm at 218 K\)\. This work is 2\-3 % lower \(p\. 633\)\. Formulas -------- No formulas are recorded. Corrections ----------- No dataset errata are recorded in this source record. Formula corrections, where recorded, appear with their formulas above. Curation notes may also discuss corrections or unresolved interpretation. Consult the :doc:`review register ` for the checks and decisions.