kossyi_1992
===========

I\. A\. Kossyi, A\. Yu\. Kostinsky, A\. A\. Matveyev and V\. P\. Silakov, "Kinetic scheme of the non\-equilibrium discharge in nitrogen\-oxygen mixtures", Plasma Sources Sci\. Technol\. 1, 207 \(1992\)

`Source record <https://github.com/LupoLab/optmat/blob/main/src/optmat/data/sources/kossyi_1992.toml>`__ · :doc:`Catalogue </the-data/sources>` · :doc:`Review register </register>`

DOI: `10\.1088/0963\-0252/1/3/011 <https://doi.org/10.1088/0963-0252/1/3/011>`__

**Source kind:** compilation

**Recorded technique:** A kinetic scheme for a non\-equilibrium discharge in N2\-O2 mixtures, for cold \(200\-500 K\), vibrationally unexcited gas\: rate constants selected from reviews and recent papers for electron\-impact excitation, dissociation and ionisation, associative ionisation, electron\-ion recombination, attachment and detachment, neutral chemistry, ion conversion and ion\-ion recombination, with a model calculation of a pulsed discharge in air \(pp\. 207\-219\)\. No measurements\.

**Materials in structured entries:** N2\+, N2O\+, NO\+, NO2\+, O2\+

**Dataset quantities:** dissociative\_recombination\_rate\_coefficient

**Contents:** 7 datasets; 0 formulas.

Curation notes
--------------

Identity checked on the first article page \(PDF page 2 = journal p\. 207; PDF page 1 is a cover sheet\)\: Kossyi, Kostinsky, Matveyev and Silakov, Plasma Sources Sci\. Technol\. 1, 207\-220 \(1992\)\. PDF page n = journal page 205 \+ n \(the page image of PDF page 4 is numbered 209\)\.

Curated\: only the dissociative recombination coefficients of the registered molecular ions \(Section 2\.3, pp\. 209\-210; page images checked at 220 dpi, the text extraction garbles the equation numbers\)\. Each is printed as k = A x \(300/T\_e\)^n cm^3 s^\-1, with 'the electron temperature T\_e \.\.\. the quantity \(2 epsilon\_e\)/\(3k\) \(epsilon\_e is the mean electron energy\); T\_e is in kelvin' \(p\. 209\)\: a power law with T\_ref = 300 K\. Every coefficient is taken by the authors from another work, cited in brackets, none of which is in the library\: \[20\] M\. H\. Bortner and T\. Baurer \(eds\), Defense Nuclear Agency Reaction Rate Handbook, 2nd ed\., DNA 1948H \(1978\), ch\. 24; \[22\] K\. Smith and R\. Thomson, Computer Modeling of Gas Lasers \(Plenum, 1978\) \(printed 'Tomson'\); \[24\] S\. I\. Kozlov, V\. A\. Vlaskov and N\. V\. Smirnova, Sov\. Space Res\. 26, 738 \(1988\)\. No uncertainty and no range of T\_e is given\. The selection favoured 'fundamental review articles containing a critical analysis' where possible \(p\. 208\)\.

NOT REGISTERED, NOTES ONLY \(p\. 209\)\: the cluster ions, \(29\) N4\+ \+ e \-\> N2 \+ N2, k29 = 2 x 10^\-6 \(300/T\_e\)^1/2; \(30\) O4\+ \+ e \-\> O2 \+ O2, 1\.4 x 10^\-6 \(300/T\_e\)^1/2; \(31\) NO\+\.NO \+ e \-\> NO \+ NO, 1\.3 x 10^\-6 \(300/T\_e\)^1/2, all from \[21\] B\. M\. Smirnov, Complex Ions \(Nauka, 1983\); \(32\)\-\(34\) NO\+\.N2, NO\+\.O2 and O2\+\.N2 \+ e set equal to k31; \(37\) N3\+ \+ e \-\> N2 \+ N, set equal to k35 \('according to \[23\] there should be fulfilled an inequality k37 \<\< 3 x 10^\-6 cm^3 s^\-1'\)\. Three\-body electron\-ion recombination \(p\. 210\) for A\+ = N2\+, O2\+, NO\+, N\+, O\+ and M = N2, O2\: \(43\) e \+ e \+ A\+, k43 = 10^\-19 \(300/T\_e\)^4\.5 cm^6 s^\-1 \[25\]; \(44\) e \+ A\+ \+ M, k44 = 6 x 10^\-27 \(300/T\_e\)^1\.5 cm^6 s^\-1 \[26\]\. The rest of the scheme \(excitation, attachment, ion conversion, neutral chemistry, ion\-ion recombination\) is not taken\: plasma kinetics is outside optmat's scope except as data \(TC\-954\)\.

Register\: TC\-976\.

**Recorded bibliographic identity status:** VALIDATED\_WITH\_WARNINGS. This concerns identification of the source; it does not establish the scientific correctness of its contents.

Datasets
--------

kossyi\_1992/dr\_N2\+\_N\_N
~~~~~~~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_N2+_N_N",
     "material": "N2+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "reproduced",
     "reproduced_from": [
       "K. Smith and R. Thomson, Computer Modeling of Gas Lasers (Plenum, New York, 1978)"
     ],
     "parameters": {
       "products": "N + N (states not given)",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 0.5
     }
   }

1 inline points in the source record.

Reaction \(38\), p\. 209\: 'N2\+ \+ e =\> N \+ N, k38 = 2\.8 x 10^\-7 x \(300/T\_e\)^1/2 cm^3 s^\-1 \[22\]'\. The products' states are not given \(the second channel, \(39\), names N\(2D\)\)\.

kossyi\_1992/dr\_N2\+\_N\_N2D
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_N2+_N_N2D",
     "material": "N2+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "reproduced",
     "reproduced_from": [
       "M. H. Bortner and T. Baurer (eds), Defense Nuclear Agency Reaction Rate Handbook, 2nd ed., DNA 1948H (General Electric, TEMPO, 1978), ch. 24"
     ],
     "parameters": {
       "products": "N + N(2D)",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 0.5
     }
   }

1 inline points in the source record.

Reaction \(39\), p\. 209\: 'N2\+ \+ e =\> N \+ N\(2D\), k39 = 2 x 10^\-7 x \(300/T\_e\)^1/2 cm^3 s^\-1 \[20\]'\. The scheme carries both N2\+ channels, \(38\) and \(39\), together 4\.8 x 10^\-7 at 300 K\.

kossyi\_1992/dr\_O2\+
~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_O2+",
     "material": "O2+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "reproduced",
     "reproduced_from": [
       "S. I. Kozlov, V. A. Vlaskov and N. V. Smirnova, Sov. Space Res. 26, 738 (1988)"
     ],
     "parameters": {
       "products": "O + O (states not given)",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 1.0
     }
   }

1 inline points in the source record.

Reaction \(40\), p\. 210\: 'O2\+ \+ e =\> O \+ O, k40 = 2 x 10^\-7 x \(300/T\_e\) cm^3 s^\-1 \[24\]' \(exponent 1, page image checked\)\.

kossyi\_1992/dr\_NO\+\_N\_O
~~~~~~~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_NO+_N_O",
     "material": "NO+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "reproduced",
     "reproduced_from": [
       "S. I. Kozlov, V. A. Vlaskov and N. V. Smirnova, Sov. Space Res. 26, 738 (1988)"
     ],
     "parameters": {
       "products": "N + O (states not given)",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 1.5
     }
   }

1 inline points in the source record.

Reaction \(41\), p\. 210\: 'NO\+ \+ e =\> N \+ O, k41 = 4 x 10^\-7 x \(300/T\_e\)^1\.5 cm^3 s^\-1 \[24\]'\.

kossyi\_1992/dr\_NO\+\_N2D\_O
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_NO+_N2D_O",
     "material": "NO+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "reproduced",
     "reproduced_from": [
       "M. H. Bortner and T. Baurer (eds), Defense Nuclear Agency Reaction Rate Handbook, 2nd ed., DNA 1948H (General Electric, TEMPO, 1978), ch. 24"
     ],
     "parameters": {
       "products": "N(2D) + O",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 1.0
     }
   }

1 inline points in the source record.

Reaction \(42\), p\. 210\: 'NO\+ \+ e =\> N\(2D\) \+ O, k42 = 3 x 10^\-7 x \(300/T\_e\) cm^3 s^\-1 \[20\]' \(exponent 1\)\.

kossyi\_1992/dr\_NO2\+
~~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_NO2+",
     "material": "NO2+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "reproduced",
     "reproduced_from": [
       "K. Smith and R. Thomson, Computer Modeling of Gas Lasers (Plenum, New York, 1978)"
     ],
     "parameters": {
       "products": "NO + O (states not given)",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 0.5
     }
   }

1 inline points in the source record.

Reaction \(35\), p\. 209\: 'NO2\+ \+ e =\> NO \+ O, k35 = 2 x 10^\-7 x \(300/T\_e\)^1/2 cm^3 s^\-1 \[22\]'\.

kossyi\_1992/dr\_N2O\+
~~~~~~~~~~~~~~~~~~~~~~

.. code-block:: text

   {
     "id": "dr_N2O+",
     "material": "N2O+",
     "table": "text",
     "quantity": "dissociative_recombination_rate_coefficient",
     "unit": "cm3/s",
     "scale": 1e-07,
     "abscissa": "none",
     "use": "excluded",
     "parameters": {
       "products": "N2 + O (states not given)",
       "law": "power_law",
       "reference_temperature_k": 300.0,
       "exponent": 0.5
     }
   }

1 inline points in the source record.

Reaction \(36\), p\. 209\: 'N2O\+ \+ e =\> N2 \+ O, k36 \-\> k35'\: the scheme sets the coefficient equal to NO2\+'s \(2 x 10^\-7 \(300/T\_e\)^1/2\), without a source\. An assumption of the scheme, not a measured or calculated value\: kept for the record, excluded\.

Formulas
--------

No formulas are recorded.

Corrections
-----------

No dataset errata are recorded in this source record.

Formula corrections, where recorded, appear with their formulas above. Curation notes may also discuss corrections or unresolved interpretation. Consult the :doc:`review register </register>` for the checks and decisions.