achtermann_1991 =============== H\. J\. Achtermann, G\. Magnus and T\. K\. Bose, "Refractivity virial coefficients of gaseous CH4, C2H4, C2H6, CO2, SF6, H2, N2, He, and Ar", J\. Chem\. Phys\. 94, 5669 \(1991\) `Source record `__ · :doc:`Catalogue ` · :doc:`Review register ` DOI: `10\.1063/1\.460478 `__ **Source kind:** measurement **Recorded technique:** Two coupled grating interferometers at the vacuum wavelength 632\.99 nm \(He\-Ne\)\: interferometer I \(two matched cells in series, with compensation chambers\) counts the fringe change Delta K during an isothermal overflow expansion into an evacuated twin cell, which measures the departure of n \- 1 from proportionality to density \(Eqs\. 7\-12\); interferometer II \(cells in parallel\) gives the absolute fringe count K and controls the expansion; expansions in both directions cancel cell mismatch \(Eq\. 8\)\. Pressures to 35 MPa \(to twice the critical density\); cell and compensation\-chamber distortion corrected \(Eqs\. 17\-19\)\. A\_R from separate absolute n\(P, T\) isotherms, the pressure from the refractive index of nitrogen calibrated against a piston gauge, extrapolated to zero density with the virial equation of state \(Eqs\. 13\-16\)\. CO2, H2, N2, He, Ar and CH4 at 323\.15 K; CH4, C2H4, C2H6, SF6 at 373\.15 K \(pp\. 5669\-5675\)\. **Materials in structured entries:** Ar, CH4, CO2, H2, He, N2, SF6 **Dataset quantities:** molar\_refractivity, refractivity\_virial\_coefficient **Contents:** 109 datasets; 0 formulas. Curation notes -------------- Definitions \(p\. 5669\)\: R\_m = \(n^2 \- 1\)/\(\(n^2 \+ 2\) rho\) = A\_R \+ B\_R rho \+ C\_R rho^2 \+ D\_R rho^3 \(Eq\. 1\), rho molar density\: A\_R is the package's molar refractivity and B\_R its refractivity\_virial\_coefficient\. The measured function is \(n \- 1\)/rho = A\_n \+ B\_n rho \+ \.\.\. \(Eq\. 2\) with A\_R = 2 A\_n/3, B\_R = 2 B\_n/3 \- A\_n^2/9, C\_R = 2 C\_n/3 \- 2 A\_n B\_n/9 \- 4 A\_n^3/27 \(Eqs\. 3\-5\)\. Accuracy \(p\. 5670\)\: 'A rough estimate of the accuracy of the measured first refractivity virial coefficient is A\_R, \+\-0\.02 % and the accuracy of the higher\-order coefficients, except for H2 and He, is B\_R, \+\-2\-5 %; C\_R, \+\-3\-5 %; and D\_R, \+\-30\-50 %'\. The B\_R, C\_R, D\_R uncertainties of Table II are 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\); the level of the A\_R uncertainties and of the literature values is not stated\. R = 8\.314471 J/\(K mol\)\. Gas purities \(Table I\)\: CH4 99\.9995 %, CO2 99\.995 %, SF6 99\.998 %, H2 99\.999 %, N2 99\.9995 %, He 99\.996 % \(Linde; O2 \< 5, N2 \< 20, H2O \< 5, Ne \< 10 ppm\), Ar 99\.998 %\. Wavelengths \(Table II caption\)\: the refractivity virial coefficients are at the vacuum wavelength 632\.99 nm 'except for the values of CH4 from Olson \(Ref\. 9\), \(lambda = 546\.2 nm\), C2H6 from Sliwinski \(Ref\. 10\), \(lambda = 589\.3 nm\), H2 from Diller \(Ref\. 8\), \(lambda = 546\.2 nm\), the theoretical value for H2 from Orcutt and Cole \(Ref\. 36\), \(lambda infinite\), and the values of He from Orcutt and Cole \(Ref\. 36\) and Kirouac and Bose \(Ref\. 55\), \(lambda infinite\)'\. The classical \(dipole\-induced\-dipole\) theoretical B\_R rows carry no wavelength and are stored at 632\.99 nm; Dacre's helium B\_eps \(Ref\. 59\) is static and stored at infinity\. 'Calculated values of A\_R have been computed from Landolt\-Boernstein Tables \(Ref\. 23\)' \(caption\)\: the A\_R of the Theory rows\. Temperatures printed '\.\.\.' are stored with the row id 'unknown' and no temperature parameter\. Extracted \(OEP 4, the quantity's order 3 and 4\), Table II, cm^9/mol^3 and cm^12/mol^4\: CH4 C\_R \-324 \+\- 5 \(323 K, this work\), \-317 \+\- 10 \(373 K, this work\), \-326 \+\- 10 \(Achtermann et al\. 1986\), \-345 \+\- 15 \(Montixi and Coulon\), \-320 \(Olson\); CO2 \-287 \+\- 8 \(this work\), \-224 \+\- 40 \(Jaeschke\); SF6 C\_R \-2783 \+\- 130 and D\_R 37 800 \+\- 8000 \(373 K, this work\); H2 \-13\.7 \+\- 2\.0 \(this work\); N2 \-99\.8 \+\- 2\.8 \(this work\), \-107 \+\- 5 \(Achtermann et al\. 1986\), \-85 \+\- 10 \(Montixi et al\.\); He\: Kirouac and Bose's C\_eps \-0\.84 \+\- 1\.20, and this work's bound \-1\.0 \< C\_R \< 0\.4 \(p\. 5680, from the fringe\-count error\); Ar \-86\.6 \+\- 2\.0 \(this work\), \-79 \+\- 10 \(Coulon et al\.\)\. Ethylene and ethane \(C2H4 C\_R \-1591 \+\- 84, D\_R 5540 \+\- 2100; C2H6 C\_R \-2227 \+\- 75, D\_R 12 400 \+\- 3500, at 373 K\) are not species\. Table III's B\_OR = B\_eps \- B\_R, B\_FIR and B\_IR \(collision\-induced absorption\) are not refractive quantities; its B\_R column repeats this work's values \(and 'estimated' ones, note c\) except CH4 at 323\.15 K, printed 6\.11 \+\- 0\.10 against Table II's 6\.08 \+\- 0\.10 \(unresolved; Table II is extracted\)\. Helium \(pp\. 5675\-5676, 5680\-5682\)\: Delta K for He at 323\.15 K \(15\.3\-35\.7 MPa, ten repetitions at 35\.7 MPa\: \-0\.58 \+\- 0\.10 fringes against K = 1351, distortion correction 0\.56\) is 'practically zero', so B\_n = C\_n = 0 and B\_R = \-0\.068 comes only from \-A\_n^2/9; without the distortion correction it would be \-0\.1\. 'To the best of our knowledge, B\_R of He has never been measured before\.' Puchalski et al\. \(2016\) find this work's helium A\_R 'ten times larger than their uncertainty' off the ab initio value \(the measured A\_R is A\_eps \+ A\_mu at 323 K\)\. Olson's reference is printed 'J\. D\. Olsen' in the reference list\. **Recorded bibliographic identity status:** VALIDATED\_WITH\_WARNINGS. This concerns identification of the source; it does not establish the scientific correctness of its contents. Datasets -------- achtermann\_1991/A\_R\_this\_work\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_this_work_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "excluded_rows": { "323": "Table II prints the same A_R (6.576 +- 0.002) on the 323 and 373 K rows; A_R was fitted on the 373.15 K isotherm only (Fig. 2 caption)" }, "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. achtermann\_1991/A\_R\_achtermann\_1986\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_achtermann_1986_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_achtermann_1986_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "H. J. Achtermann, T. K. Bose, M. Jaeschke and J. M. St-Arnaud, Int. J. Thermophys. 7, 357 (1986)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Achtermann et al\. \(Ref\. 25\), the same apparatus without the distortion correction \(p\. 5679\)\: superseded\. achtermann\_1991/A\_R\_buckingham\_graham\_1974\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_buckingham_graham_1974_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_buckingham_graham_1974_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/A\_R\_burns\_1986\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_burns_1986_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_burns_1986_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/A\_R\_montixi\_coulon\_1983\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_montixi_coulon_1983_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_montixi_coulon_1983_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi and R. Coulon, C. R. Acad. Sci. t. 296, 135 (1983)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Montixi and Coulon \(Ref\. 26\), absolute method\. achtermann\_1991/A\_R\_olson\_1975\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_olson_1975_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_olson_1975_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. D. Olsen, J. Chem. Phys. 63, 474 (1975)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Olson \(Ref\. 9; 'Olsen' in the reference list\), absolute method, 546\.2 nm \(caption\)\. achtermann\_1991/A\_R\_st\_arnaud\_bose\_1976\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_st_arnaud_bose_1976_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_st_arnaud_bose_1976_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 65, 4854 (1976)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: St\-Arnaud and Bose \(Ref\. 13\), differential, 632\.99 nm\. achtermann\_1991/A\_R\_theory\_buckingham\_graham\_1974\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_theory_buckingham_graham_1974_CH4", "material": "CH4", "file": "CH4/achtermann_1991__A_R_theory_buckingham_graham_1974_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "Landolt-Boernstein, Zahlenwerte und Funktionen (Springer, Berlin, 1962), Band II, Teil 8", "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\), row 'Theory \(Ref\. 12\)'\: 'Calculated values of A\_R have been computed from Landolt\-Boernstein Tables \(Ref\. 23\)' \(caption\); whether this A\_R is the authors' Landolt\-Boernstein value or the theory paper's is not stated\. achtermann\_1991/B\_R\_this\_work\_323\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_323_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_this_work_323_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. Table III repeats this work's 323\.15 K value as 6\.11 \+\- 0\.10 \(Table II\: 6\.08 \+\- 0\.10\); unresolved, Table II is taken\. achtermann\_1991/B\_R\_this\_work\_373\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_373_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_this_work_373_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 373.0 } } B\_R \(cm^6/mol^2\) of Table II at 373 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/B\_R\_achtermann\_1986\_323\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_achtermann_1986_323_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_achtermann_1986_323_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "H. J. Achtermann, T. K. Bose, M. Jaeschke and J. M. St-Arnaud, Int. J. Thermophys. 7, 357 (1986)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: Achtermann et al\. \(Ref\. 25\), the same apparatus without the distortion correction \(p\. 5679\)\: superseded\. achtermann\_1991/B\_R\_buckingham\_graham\_1974\_299\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_buckingham_graham_1974_299_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_buckingham_graham_1974_299_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 299.0 } } B\_R \(cm^6/mol^2\) of Table II at 299 K\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/B\_R\_burns\_1986\_unknown\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_burns_1986_unknown_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_burns_1986_unknown_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "uncertainty": { "column": true, "level": "not stated" } } B\_R \(cm^6/mol^2\) of Table II, temperature not stated \('\.\.\.'\)\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/B\_R\_montixi\_coulon\_1983\_298\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_montixi_coulon_1983_298_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_montixi_coulon_1983_298_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi and R. Coulon, C. R. Acad. Sci. t. 296, 135 (1983)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Montixi and Coulon \(Ref\. 26\), absolute method\. achtermann\_1991/B\_R\_olson\_1975\_220\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_olson_1975_220_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_olson_1975_220_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. D. Olsen, J. Chem. Phys. 63, 474 (1975)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 220.0 } } B\_R \(cm^6/mol^2\) of Table II at 220 K\: Olson \(Ref\. 9; 'Olsen' in the reference list\), absolute method, 546\.2 nm \(caption\)\. achtermann\_1991/B\_R\_st\_arnaud\_bose\_1976\_302\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_st_arnaud_bose_1976_302_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_st_arnaud_bose_1976_302_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 65, 4854 (1976)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 302.0 } } B\_R \(cm^6/mol^2\) of Table II at 302 K\: St\-Arnaud and Bose \(Ref\. 13\), differential, 632\.99 nm\. achtermann\_1991/B\_R\_theory\_buckingham\_graham\_1974\_298\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_buckingham_graham_1974_298_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_theory_buckingham_graham_1974_298_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Buckingham and Graham \(Ref\. 12\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_burns\_1986\_298\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_burns_1986_298_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_theory_burns_1986_298_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Burns et al\. \(Ref\. 6\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_st\_arnaud\_bose\_1976\_302\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_st_arnaud_bose_1976_302_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_R_theory_st_arnaud_bose_1976_302_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 65, 4854 (1976)" ], "parameters": { "temperature_k": 302.0 } } B\_R \(cm^6/mol^2\) of Table II at 302 K\: theoretical value of St\-Arnaud and Bose \(Ref\. 13\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_eps\_bose\_1972\_279\.8\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_bose_1972_279.8_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_eps_bose_1972_279.8_CH4.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "bose_1972" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 279.8 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 279\.8 K\: Bose, Sochanski and Cole \(1972\), Table I, reprinted digit for digit with its error \(checked against the original, 2026\-09\-26\)\. The original states its errors as three standard deviations of the least\-squares fit \(bose\_1972, p\. 3\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_bose\_1972\_322\.5\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_bose_1972_322.5_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_eps_bose_1972_322.5_CH4.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "bose_1972" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 322.5 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 322\.5 K\: Bose, Sochanski and Cole \(1972\), Table I, reprinted digit for digit with its error \(checked against the original, 2026\-09\-26\)\. The original states its errors as three standard deviations of the least\-squares fit \(bose\_1972, p\. 3\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_bose\_1972\_373\.4\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_bose_1972_373.4_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_eps_bose_1972_373.4_CH4.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "bose_1972" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 373.4 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 373\.4 K\: Bose, Sochanski and Cole \(1972\), Table I, reprinted digit for digit with its error \(checked against the original, 2026\-09\-26\)\. The original states its errors as three standard deviations of the least\-squares fit \(bose\_1972, p\. 3\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_extrapolated\_303\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_extrapolated_303_CH4", "material": "CH4", "file": "CH4/achtermann_1991__B_eps_extrapolated_303_CH4.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "check", "parameters": { "temperature_k": 303.0 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 303 K\: marked 'a', 'Extrapolated values' \(Table III note\), the authors' extrapolation of the literature B\_eps to 303 K for the comparison of Table III; not a measurement\. achtermann\_1991/A\_R\_this\_work\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_CO2", "material": "CO2", "file": "CO2/achtermann_1991__A_R_this_work_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. achtermann\_1991/A\_R\_buckingham\_graham\_1974\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_buckingham_graham_1974_CO2", "material": "CO2", "file": "CO2/achtermann_1991__A_R_buckingham_graham_1974_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/A\_R\_burns\_1986\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_burns_1986_CO2", "material": "CO2", "file": "CO2/achtermann_1991__A_R_burns_1986_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/A\_R\_jaeschke\_1986\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_jaeschke_1986_CO2", "material": "CO2", "file": "CO2/achtermann_1991__A_R_jaeschke_1986_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "M. Jaeschke, Gas Quality, edited by G. J. van Rossum (Elsevier, Amsterdam, 1986)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Jaeschke \(Ref\. 28\), fit of optical PVT data to Burnett data\. achtermann\_1991/A\_R\_st\_arnaud\_bose\_1979\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_st_arnaud_bose_1979_CO2", "material": "CO2", "file": "CO2/achtermann_1991__A_R_st_arnaud_bose_1979_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: St\-Arnaud and Bose \(Ref\. 14\), differential, 632\.99 nm\. achtermann\_1991/A\_R\_theory\_st\_arnaud\_bose\_1979\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_theory_st_arnaud_bose_1979_CO2", "material": "CO2", "file": "CO2/achtermann_1991__A_R_theory_st_arnaud_bose_1979_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "Landolt-Boernstein, Zahlenwerte und Funktionen (Springer, Berlin, 1962), Band II, Teil 8", "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\), row 'Theory \(Ref\. 14\)'\: 'Calculated values of A\_R have been computed from Landolt\-Boernstein Tables \(Ref\. 23\)' \(caption\); whether this A\_R is the authors' Landolt\-Boernstein value or the theory paper's is not stated\. achtermann\_1991/B\_R\_this\_work\_323\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_323_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_this_work_323_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/B\_R\_buckingham\_graham\_1974\_299\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_buckingham_graham_1974_299_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_buckingham_graham_1974_299_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 299.0 } } B\_R \(cm^6/mol^2\) of Table II at 299 K\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/B\_R\_burns\_1986\_298\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_burns_1986_298_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_burns_1986_298_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/B\_R\_jaeschke\_1986\_320\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_jaeschke_1986_320_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_jaeschke_1986_320_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "M. Jaeschke, Gas Quality, edited by G. J. van Rossum (Elsevier, Amsterdam, 1986)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 320.0 } } B\_R \(cm^6/mol^2\) of Table II at 320 K\: Jaeschke \(Ref\. 28\), fit of optical PVT data to Burnett data\. achtermann\_1991/B\_R\_st\_arnaud\_bose\_1979\_323\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_st_arnaud_bose_1979_323_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_st_arnaud_bose_1979_323_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: St\-Arnaud and Bose \(Ref\. 14\), differential, 632\.99 nm\. achtermann\_1991/B\_R\_theory\_buckingham\_graham\_1974\_298\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_buckingham_graham_1974_298_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_theory_buckingham_graham_1974_298_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Buckingham and Graham \(Ref\. 12\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_burns\_1986\_298\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_burns_1986_298_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_theory_burns_1986_298_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Burns et al\. \(Ref\. 6\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_st\_arnaud\_bose\_1979\_unknown\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_st_arnaud_bose_1979_unknown_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_R_theory_st_arnaud_bose_1979_unknown_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ] } B\_R \(cm^6/mol^2\) of Table II, temperature not stated \('\.\.\.'\)\: theoretical value of St\-Arnaud and Bose \(Ref\. 14\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_eps\_bose\_cole\_1970\_302\.6\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_bose_cole_1970_302.6_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_eps_bose_cole_1970_302.6_CO2.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "bose_1970" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 302.6 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 302\.6 K\: T\. K\. Bose and R\. H\. Cole, J\. Chem\. Phys\. 52, 140 \(1970\) = bose\_1970 \(re\-pointed 2026\-09\-27\), its Table II value at 29\.4 degrees C, 57\.6 \+\- 0\.90, reprinted as 57\.6 \+\- 0\.9 \(the error rounded; checked\)\. The original's errors are three standard deviations of the least\-squares fit \(bose\_1970, pp\. 141\-142\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_bose\_cole\_1970\_322\.9\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_bose_cole_1970_322.9_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_eps_bose_cole_1970_322.9_CO2.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "bose_1970" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 322.9 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 322\.9 K\: T\. K\. Bose and R\. H\. Cole, J\. Chem\. Phys\. 52, 140 \(1970\) = bose\_1970 \(re\-pointed 2026\-09\-27\), its Table II value at 49\.7 degrees C, 50\.7 \+\- 0\.93, reprinted as 50\.7 \+\- 0\.9 \(the error rounded; checked\)\. The original's errors are three standard deviations of the least\-squares fit \(bose\_1970, pp\. 141\-142\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_extrapolated\_296\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_extrapolated_296_CO2", "material": "CO2", "file": "CO2/achtermann_1991__B_eps_extrapolated_296_CO2.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "check", "parameters": { "temperature_k": 296.0 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 296 K\: marked 'a', 'Extrapolated values' \(Table III note\), the authors' extrapolation of the literature B\_eps to 296 K for the comparison of Table III; not a measurement\. achtermann\_1991/A\_R\_this\_work\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_SF6", "material": "SF6", "file": "SF6/achtermann_1991__A_R_this_work_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. achtermann\_1991/A\_R\_buckingham\_graham\_1974\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_buckingham_graham_1974_SF6", "material": "SF6", "file": "SF6/achtermann_1991__A_R_buckingham_graham_1974_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/A\_R\_burns\_1986\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_burns_1986_SF6", "material": "SF6", "file": "SF6/achtermann_1991__A_R_burns_1986_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/A\_R\_st\_arnaud\_bose\_1979\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_st_arnaud_bose_1979_SF6", "material": "SF6", "file": "SF6/achtermann_1991__A_R_st_arnaud_bose_1979_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: St\-Arnaud and Bose \(Ref\. 14\), differential, 632\.99 nm\. achtermann\_1991/A\_R\_theory\_st\_arnaud\_bose\_1979\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_theory_st_arnaud_bose_1979_SF6", "material": "SF6", "file": "SF6/achtermann_1991__A_R_theory_st_arnaud_bose_1979_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "Landolt-Boernstein, Zahlenwerte und Funktionen (Springer, Berlin, 1962), Band II, Teil 8", "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\), row 'Theory \(Ref\. 14\)'\: 'Calculated values of A\_R have been computed from Landolt\-Boernstein Tables \(Ref\. 23\)' \(caption\); whether this A\_R is the authors' Landolt\-Boernstein value or the theory paper's is not stated\. achtermann\_1991/B\_R\_this\_work\_373\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_373_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_this_work_373_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 373.0 } } B\_R \(cm^6/mol^2\) of Table II at 373 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/B\_R\_buckingham\_graham\_1974\_299\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_buckingham_graham_1974_299_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_buckingham_graham_1974_299_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 299.0 } } B\_R \(cm^6/mol^2\) of Table II at 299 K\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/B\_R\_burns\_1986\_298\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_burns_1986_298_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_burns_1986_298_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/B\_R\_st\_arnaud\_bose\_1979\_323\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_st_arnaud_bose_1979_323_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_st_arnaud_bose_1979_323_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: St\-Arnaud and Bose \(Ref\. 14\), differential, 632\.99 nm\. achtermann\_1991/B\_R\_theory\_buckingham\_graham\_1974\_298\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_buckingham_graham_1974_298_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_theory_buckingham_graham_1974_298_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Buckingham and Graham \(Ref\. 12\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_burns\_1986\_298\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_burns_1986_298_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_theory_burns_1986_298_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Burns et al\. \(Ref\. 6\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_st\_arnaud\_bose\_1979\_unknown\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_st_arnaud_bose_1979_unknown_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_R_theory_st_arnaud_bose_1979_unknown_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. M. St-Arnaud and T. K. Bose, J. Chem. Phys. 71, 4951 (1979)" ] } B\_R \(cm^6/mol^2\) of Table II, temperature not stated \('\.\.\.'\)\: theoretical value of St\-Arnaud and Bose \(Ref\. 14\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_eps\_extrapolated\_298\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_extrapolated_298_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_eps_extrapolated_298_SF6.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "check", "parameters": { "temperature_k": 298.0 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 298 K\: marked 'a', 'Extrapolated values' \(Table III note\), the authors' extrapolation of the literature B\_eps to 298 K for the comparison of Table III; not a measurement\. achtermann\_1991/B\_eps\_hosticka\_bose\_1974\_323\.3\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_hosticka_bose_1974_323.3_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_eps_hosticka_bose_1974_323.3_SF6.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "hosticka_1974" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.3 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 323\.3 K\: C\. Hosticka and T\. K\. Bose, J\. Chem\. Phys\. 60, 1318 \(1974\) = hosticka\_1974 \(re\-pointed 2026\-09\-27\), its Table I value 63\.31 \+\- 2\.80, digit for digit \(checked\)\. The original's errors are three times the standard deviation \(hosticka\_1974, p\. 1319\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_hosticka\_bose\_1974\_348\.3\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_hosticka_bose_1974_348.3_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_eps_hosticka_bose_1974_348.3_SF6.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "hosticka_1974" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 348.3 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 348\.3 K\: C\. Hosticka and T\. K\. Bose, J\. Chem\. Phys\. 60, 1318 \(1974\) = hosticka\_1974 \(re\-pointed 2026\-09\-27\), its Table I value 60\.54 \+\- 1\.45, digit for digit \(checked\)\. The original's errors are three times the standard deviation \(hosticka\_1974, p\. 1319\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/B\_eps\_hosticka\_bose\_1974\_373\.9\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_hosticka_bose_1974_373.9_SF6", "material": "SF6", "file": "SF6/achtermann_1991__B_eps_hosticka_bose_1974_373.9_SF6.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "hosticka_1974" ], "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 373.9 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 373\.9 K\: C\. Hosticka and T\. K\. Bose, J\. Chem\. Phys\. 60, 1318 \(1974\) = hosticka\_1974 \(re\-pointed 2026\-09\-27\), its Table I value at 373\.9 K\. The original prints 58\.89 \+\- 4\.70; this reprint has 58\.84 \+\- 4\.70 \(a transcription difference of 0\.05 in the reprint; the value here is kept as printed\)\. The original's errors are three times the standard deviation \(hosticka\_1974, p\. 1319\)\: level corrected from 'not stated' to '3 sigma'\. achtermann\_1991/A\_R\_this\_work\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_H2", "material": "H2", "file": "H2/achtermann_1991__A_R_this_work_H2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. achtermann\_1991/A\_R\_diller\_1968\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_diller_1968_H2", "material": "H2", "file": "H2/achtermann_1991__A_R_diller_1968_H2.csv", "table": "tbl_dffe72791eb0", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "D. E. Diller, J. Chem. Phys. 49, 3096 (1968)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Diller \(Ref\. 8\), 546\.2 nm \(caption\)\. achtermann\_1991/B\_R\_this\_work\_323\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_323_H2", "material": "H2", "file": "H2/achtermann_1991__B_R_this_work_323_H2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/B\_R\_theory\_orcutt\_1967\_unknown\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_orcutt_1967_unknown_H2", "material": "H2", "file": "H2/achtermann_1991__B_R_theory_orcutt_1967_unknown_H2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "orcutt_1967" ] } B\_R \(cm^6/mol^2\) of Table II, temperature not stated \('\.\.\.'\)\: theoretical value of Orcutt and Cole \(Ref\. 36\), a static dielectric B\_eps \(caption\: lambda infinite\)\. achtermann\_1991/A\_R\_this\_work\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_N2", "material": "N2", "file": "N2/achtermann_1991__A_R_this_work_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. achtermann\_1991/A\_R\_achtermann\_1986\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_achtermann_1986_N2", "material": "N2", "file": "N2/achtermann_1991__A_R_achtermann_1986_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "H. J. Achtermann, T. K. Bose, M. Jaeschke and J. M. St-Arnaud, Int. J. Thermophys. 7, 357 (1986)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Achtermann et al\. \(Ref\. 25\), the same apparatus without the distortion correction \(p\. 5679\)\: superseded\. achtermann\_1991/A\_R\_buckingham\_graham\_1974\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_buckingham_graham_1974_N2", "material": "N2", "file": "N2/achtermann_1991__A_R_buckingham_graham_1974_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/A\_R\_burns\_1986\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_burns_1986_N2", "material": "N2", "file": "N2/achtermann_1991__A_R_burns_1986_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/A\_R\_montixi\_1983\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_montixi_1983_N2", "material": "N2", "file": "N2/achtermann_1991__A_R_montixi_1983_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi, R. Coulon and R. Occelli, Can. J. Phys. 61, 473 (1983)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Montixi et al\. \(Ref\. 7\), absolute method, 4\-40 MPa\. achtermann\_1991/A\_R\_theory\_burns\_1986\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_theory_burns_1986_N2", "material": "N2", "file": "N2/achtermann_1991__A_R_theory_burns_1986_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "Landolt-Boernstein, Zahlenwerte und Funktionen (Springer, Berlin, 1962), Band II, Teil 8", "burns_1986" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\), row 'Theory \(Ref\. 6\)'\: 'Calculated values of A\_R have been computed from Landolt\-Boernstein Tables \(Ref\. 23\)' \(caption\); whether this A\_R is the authors' Landolt\-Boernstein value or the theory paper's is not stated\. achtermann\_1991/B\_R\_this\_work\_323\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_323_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_this_work_323_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/B\_R\_achtermann\_1986\_323\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_achtermann_1986_323_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_achtermann_1986_323_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "H. J. Achtermann, T. K. Bose, M. Jaeschke and J. M. St-Arnaud, Int. J. Thermophys. 7, 357 (1986)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: Achtermann et al\. \(Ref\. 25\), the same apparatus without the distortion correction \(p\. 5679\)\: superseded\. achtermann\_1991/B\_R\_buckingham\_graham\_1974\_299\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_buckingham_graham_1974_299_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_buckingham_graham_1974_299_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 299.0 } } B\_R \(cm^6/mol^2\) of Table II at 299 K\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/B\_R\_burns\_1986\_298\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_burns_1986_298_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_burns_1986_298_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/B\_R\_montixi\_1983\_298\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_montixi_1983_298_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_montixi_1983_298_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi, R. Coulon and R. Occelli, Can. J. Phys. 61, 473 (1983)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Montixi et al\. \(Ref\. 7\), absolute method, 4\-40 MPa\. achtermann\_1991/B\_R\_theory\_buckingham\_graham\_1974\_298\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_buckingham_graham_1974_298_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_theory_buckingham_graham_1974_298_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Buckingham and Graham \(Ref\. 12\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_burns\_1986\_298\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_burns_1986_298_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_theory_burns_1986_298_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Burns et al\. \(Ref\. 6\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_montixi\_1983\_298\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_montixi_1983_298_N2", "material": "N2", "file": "N2/achtermann_1991__B_R_theory_montixi_1983_298_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi, R. Coulon and R. Occelli, Can. J. Phys. 61, 473 (1983)" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Montixi et al\. \(Ref\. 7\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_eps\_huot\_bose\_323\.1\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_eps_huot_bose_323.1_N2", "material": "N2", "file": "N2/achtermann_1991__B_eps_huot_bose_323.1_N2.csv", "table": "tbl_b69cbca038de", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. Huot and T. K. Bose (unpublished)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 323.1 } } B\_eps \(cm^6/mol^2, static dielectric second virial coefficient\) of Table III at 323\.1 K\: J\. Huot and T\. K\. Bose \(unpublished\), as printed with its uncertainty in Table III\. achtermann\_1991/A\_R\_this\_work\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_He", "material": "He", "file": "He/achtermann_1991__A_R_this_work_He.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. Judged 'ten times' its uncertainty above the ab initio value by puchalski\_2016 \(0\.52026 cm^3/mol at 632\.99 nm; stone\_2004\: 7e\-8 in n at 1 atm\)\. achtermann\_1991/A\_R\_kirouac\_bose\_1976\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_kirouac_bose_1976_He", "material": "He", "file": "He/achtermann_1991__A_R_kirouac_bose_1976_He.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "S. Kirouac and T. K. Bose, J. Chem. Phys. 64, 1580 (1976)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Kirouac and Bose \(Ref\. 55\), dielectric \(static; caption\: lambda infinite\), i\.e\. A\_eps and B\_eps; their B uncertainty printed \+\-0\.0009 is 'changed to \+\-0\.009 because of a printing error in the earlier paper' \(Table II note a\)\. achtermann\_1991/A\_R\_orcutt\_1967\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_orcutt_1967_He", "material": "He", "file": "He/achtermann_1991__A_R_orcutt_1967_He.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "orcutt_1967" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Orcutt and Cole \(Ref\. 36\), dielectric \(static; caption\: lambda infinite\), i\.e\. A\_eps and B\_eps\. achtermann\_1991/B\_R\_this\_work\_323\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_323_He", "material": "He", "file": "He/achtermann_1991__B_R_this_work_323_He.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. For He the corrected fringe count Delta K is 'practically zero' \(F a straight line along the x axis, 15\.3\-35\.7 MPa\)\: B\_n = 0 and B\_R = \-A\_n^2/9 only \(pp\. 5675\-5676\); without the distortion correction B\_R would be \-0\.1\. Puchalski et al\. 2016 recompute b\_n = 0\.000\(15\) from it and predict 0\.0184\(3\) and 0\.0150\(3\) \(b\_R about \-0\.056 and \-0\.058\) at 303 and 323 K\. achtermann\_1991/B\_R\_kirouac\_bose\_1976\_303\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_kirouac_bose_1976_303_He", "material": "He", "file": "He/achtermann_1991__B_R_kirouac_bose_1976_303_He.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "S. Kirouac and T. K. Bose, J. Chem. Phys. 64, 1580 (1976)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 303.0 } } B\_R \(cm^6/mol^2\) of Table II at 303 K\: Kirouac and Bose \(Ref\. 55\), dielectric \(static; caption\: lambda infinite\), i\.e\. A\_eps and B\_eps; their B uncertainty printed \+\-0\.0009 is 'changed to \+\-0\.009 because of a printing error in the earlier paper' \(Table II note a\)\. achtermann\_1991/B\_R\_orcutt\_1967\_323\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_orcutt_1967_323_He", "material": "He", "file": "He/achtermann_1991__B_R_orcutt_1967_323_He.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "orcutt_1967" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: Orcutt and Cole \(Ref\. 36\), dielectric \(static; caption\: lambda infinite\), i\.e\. A\_eps and B\_eps\. achtermann\_1991/B\_R\_theory\_dacre\_1982\_294\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_dacre_1982_294_He", "material": "He", "file": "He/achtermann_1991__B_R_theory_dacre_1982_294_He.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "P. D. Dacre, Mol. Phys. 45, 17 (1982)" ], "parameters": { "temperature_k": 294.0 } } B\_R \(cm^6/mol^2\) of Table II at 294 K\: theoretical value of Dacre \(Ref\. 59\), a static dielectric B\_eps \(caption\: lambda infinite\); 'Dacre calculated at 294 K the total SCF \+ CI trace and found B\_eps \(SCF \+ CI\) = \-0\.062 cm6/mol2' \(p\. 5682\), HFDHE2 potential\. achtermann\_1991/A\_R\_this\_work\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_this_work_Ar", "material": "Ar", "file": "Ar/achtermann_1991__A_R_this_work_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: this work, from the absolute n\(P, T\) isotherm and Eq\. \(15\) \(Fig\. 2\); vacuum 632\.99 nm; A\_R includes the magnetizability term \(negligible here\)\. Printed '4\.196 \+\- 0\.0002'\: the value has one digit fewer than its uncertainty \(4\.1960 presumably\)\. achtermann\_1991/A\_R\_buckingham\_graham\_1974\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_buckingham_graham_1974_Ar", "material": "Ar", "file": "Ar/achtermann_1991__A_R_buckingham_graham_1974_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/A\_R\_burns\_1986\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_burns_1986_Ar", "material": "Ar", "file": "Ar/achtermann_1991__A_R_burns_1986_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ] } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/A\_R\_coulon\_1981\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "A_R_coulon_1981_Ar", "material": "Ar", "file": "Ar/achtermann_1991__A_R_coulon_1981_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "molar_refractivity", "unit": "cm3/mol", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "R. Coulon, G. Montixi and R. Occelli, Can. J. Phys. 59, 1555 (1981)" ], "uncertainty": { "column": true, "level": "not stated" } } A\_R \(cm^3/mol\) of Table II, rows by temperature \(K\)\: Coulon et al\. \(Ref\. 29\), absolute method\. achtermann\_1991/B\_R\_this\_work\_323\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_this_work_323_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_this_work_323_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "temperature_k": 323.0 } } B\_R \(cm^6/mol^2\) of Table II at 323 K\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/B\_R\_buckingham\_graham\_1974\_299\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_buckingham_graham_1974_299_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_buckingham_graham_1974_299_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 299.0 } } B\_R \(cm^6/mol^2\) of Table II at 299 K\: Buckingham and Graham \(Ref\. 12\), differential method to about 0\.5 MPa\. achtermann\_1991/B\_R\_burns\_1986\_298\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_burns_1986_298_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_burns_1986_298_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Burns et al\. \(Ref\. 6\), differential to about 0\.5 MPa\. achtermann\_1991/B\_R\_coulon\_1981\_298\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_coulon_1981_298_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_coulon_1981_298_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "R. Coulon, G. Montixi and R. Occelli, Can. J. Phys. 59, 1555 (1981)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: Coulon et al\. \(Ref\. 29\), absolute method\. achtermann\_1991/B\_R\_theory\_bose\_1988\_303\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_bose_1988_303_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_theory_bose_1988_303_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "T. K. Bose, K. Boudjarane, J. Huot and J. M. St-Arnaud, J. Chem. Phys. 89, 7435 (1988)" ], "parameters": { "temperature_k": 303.0 } } B\_R \(cm^6/mol^2\) of Table II at 303 K\: theoretical value of Bose et al\. \(Ref\. 15\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_buckingham\_graham\_1974\_298\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_buckingham_graham_1974_298_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_theory_buckingham_graham_1974_298_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "A. D. Buckingham and C. Graham, Proc. R. Soc. A 336, 275 (1974)" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Buckingham and Graham \(Ref\. 12\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/B\_R\_theory\_burns\_1986\_298\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "B_R_theory_burns_1986_298_Ar", "material": "Ar", "file": "Ar/achtermann_1991__B_R_theory_burns_1986_298_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm6/mol2", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "burns_1986" ], "parameters": { "temperature_k": 298.0 } } B\_R \(cm^6/mol^2\) of Table II at 298 K\: theoretical value of Burns et al\. \(Ref\. 6\), a classical dipole\-induced\-dipole \(Lennard\-Jones\) estimate; the wavelength of the calculation is not stated \(632\.99 nm assumed\)\. achtermann\_1991/C\_R\_this\_work\_323\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_323_CH4", "material": "CH4", "file": "CH4/achtermann_1991__C_R_this_work_323_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_this\_work\_323\_CH4\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. Table III repeats this work's 323\.15 K value as 6\.11 \+\- 0\.10 \(Table II\: 6\.08 \+\- 0\.10\); unresolved, Table II is taken\. achtermann\_1991/C\_R\_this\_work\_373\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_373_CH4", "material": "CH4", "file": "CH4/achtermann_1991__C_R_this_work_373_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 373.0 } } C\_R \(cm^9/mol^3\) of Table II at 373 K, the row of B\_R\_this\_work\_373\_CH4\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/C\_R\_achtermann\_1986\_323\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_achtermann_1986_323_CH4", "material": "CH4", "file": "CH4/achtermann_1991__C_R_achtermann_1986_323_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "H. J. Achtermann, T. K. Bose, M. Jaeschke and J. M. St-Arnaud, Int. J. Thermophys. 7, 357 (1986)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_achtermann\_1986\_323\_CH4\: Achtermann et al\. \(Ref\. 25\), the same apparatus without the distortion correction \(p\. 5679\)\: superseded\. achtermann\_1991/C\_R\_montixi\_coulon\_1983\_298\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_montixi_coulon_1983_298_CH4", "material": "CH4", "file": "CH4/achtermann_1991__C_R_montixi_coulon_1983_298_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi and R. Coulon, C. R. Acad. Sci. t. 296, 135 (1983)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 298.0 } } C\_R \(cm^9/mol^3\) of Table II at 298 K, the row of B\_R\_montixi\_coulon\_1983\_298\_CH4\: Montixi and Coulon \(Ref\. 26\), absolute method\. achtermann\_1991/C\_R\_olson\_1975\_220\_CH4 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_olson_1975_220_CH4", "material": "CH4", "file": "CH4/achtermann_1991__C_R_olson_1975_220_CH4.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "J. D. Olsen, J. Chem. Phys. 63, 474 (1975)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 220.0 } } C\_R \(cm^9/mol^3\) of Table II at 220 K, the row of B\_R\_olson\_1975\_220\_CH4\: Olson \(Ref\. 9; 'Olsen' in the reference list\), absolute method, 546\.2 nm \(caption\)\. achtermann\_1991/C\_R\_this\_work\_323\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_323_CO2", "material": "CO2", "file": "CO2/achtermann_1991__C_R_this_work_323_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_this\_work\_323\_CO2\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/C\_R\_jaeschke\_1986\_320\_CO2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_jaeschke_1986_320_CO2", "material": "CO2", "file": "CO2/achtermann_1991__C_R_jaeschke_1986_320_CO2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "M. Jaeschke, Gas Quality, edited by G. J. van Rossum (Elsevier, Amsterdam, 1986)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 320.0 } } C\_R \(cm^9/mol^3\) of Table II at 320 K, the row of B\_R\_jaeschke\_1986\_320\_CO2\: Jaeschke \(Ref\. 28\), fit of optical PVT data to Burnett data\. achtermann\_1991/C\_R\_this\_work\_373\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_373_SF6", "material": "SF6", "file": "SF6/achtermann_1991__C_R_this_work_373_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 373.0 } } C\_R \(cm^9/mol^3\) of Table II at 373 K, the row of B\_R\_this\_work\_373\_SF6\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/D\_R\_this\_work\_373\_SF6 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "D_R_this_work_373_SF6", "material": "SF6", "file": "SF6/achtermann_1991__D_R_this_work_373_SF6.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm12/mol4", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 4, "temperature_k": 373.0 } } D\_R \(cm^12/mol^4\) of Table II at 373 K, the row of B\_R\_this\_work\_373\_SF6\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/C\_R\_this\_work\_323\_H2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_323_H2", "material": "H2", "file": "H2/achtermann_1991__C_R_this_work_323_H2.csv", "table": "tbl_dffe72791eb0", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_this\_work\_323\_H2\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/C\_R\_this\_work\_323\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_323_N2", "material": "N2", "file": "N2/achtermann_1991__C_R_this_work_323_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_this\_work\_323\_N2\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/C\_R\_achtermann\_1986\_323\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_achtermann_1986_323_N2", "material": "N2", "file": "N2/achtermann_1991__C_R_achtermann_1986_323_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "H. J. Achtermann, T. K. Bose, M. Jaeschke and J. M. St-Arnaud, Int. J. Thermophys. 7, 357 (1986)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_achtermann\_1986\_323\_N2\: Achtermann et al\. \(Ref\. 25\), the same apparatus without the distortion correction \(p\. 5679\)\: superseded\. achtermann\_1991/C\_R\_montixi\_1983\_298\_N2 ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_montixi_1983_298_N2", "material": "N2", "file": "N2/achtermann_1991__C_R_montixi_1983_298_N2.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "G. Montixi, R. Coulon and R. Occelli, Can. J. Phys. 61, 473 (1983)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 298.0 } } C\_R \(cm^9/mol^3\) of Table II at 298 K, the row of B\_R\_montixi\_1983\_298\_N2\: Montixi et al\. \(Ref\. 7\), absolute method, 4\-40 MPa\. achtermann\_1991/C\_R\_kirouac\_bose\_1976\_303\_He ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_kirouac_bose_1976_303_He", "material": "He", "file": "He/achtermann_1991__C_R_kirouac_bose_1976_303_He.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "S. Kirouac and T. K. Bose, J. Chem. Phys. 64, 1580 (1976)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 303.0 } } C\_eps \(cm^9/mol^3; static\) of Table II at 303 K, the row of B\_R\_kirouac\_bose\_1976\_303\_He\: Kirouac and Bose \(Ref\. 55\), dielectric \(static; caption\: lambda infinite\), i\.e\. A\_eps and B\_eps; their B uncertainty printed \+\-0\.0009 is 'changed to \+\-0\.009 because of a printing error in the earlier paper' \(Table II note a\)\. achtermann\_1991/C\_R\_this\_work\_323\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_this_work_323_Ar", "material": "Ar", "file": "Ar/achtermann_1991__C_R_this_work_323_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "primary", "uncertainty": { "column": true, "level": "3 sigma" }, "parameters": { "order": 3, "temperature_k": 323.0 } } C\_R \(cm^9/mol^3\) of Table II at 323 K, the row of B\_R\_this\_work\_323\_Ar\: this work, differential overflow method \(Eq\. 8, 20\); uncertainty 'three standard deviations from the least\-squares fit as well as errors due to cell distortion and adsorption' \(p\. 5675\) \(level\: 3 sigma\)\. achtermann\_1991/C\_R\_coulon\_1981\_298\_Ar ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ .. code-block:: text { "id": "C_R_coulon_1981_298_Ar", "material": "Ar", "file": "Ar/achtermann_1991__C_R_coulon_1981_298_Ar.csv", "table": "tbl_5293ebc0b026", "quantity": "refractivity_virial_coefficient", "unit": "cm9/mol3", "abscissa_unit": "nm", "wavelength_medium": "vacuum", "use": "reproduced", "reproduced_from": [ "R. Coulon, G. Montixi and R. Occelli, Can. J. Phys. 59, 1555 (1981)" ], "uncertainty": { "column": true, "level": "not stated" }, "parameters": { "order": 3, "temperature_k": 298.0 } } C\_R \(cm^9/mol^3\) of Table II at 298 K, the row of B\_R\_coulon\_1981\_298\_Ar\: Coulon et al\. \(Ref\. 29\), absolute method\. Formulas -------- No formulas are recorded. Corrections ----------- No dataset errata are recorded in this source record. Formula corrections, where recorded, appear with their formulas above. Curation notes may also discuss corrections or unresolved interpretation. Consult the :doc:`review register ` for the checks and decisions.